First, I don't know the answer. I'm speculating as much as you are. My suspicion is that the angle doesn't matter because within practical limits, the difference to the gas flow would be too small to measure. I'd buy it if the case was silly - like 1" diameter .17 caliber with a 60 degree shoulder. But 30 vs 40 degrees with a normal sized case head and caliber?
Think about barrel time - it's roughly .002 seconds give or take. That's the amount of time that the flame has to transfer heat to the bore. How much of a delay would the shoulder angle really make? I have a hard time believing it's enough to change barrel time significantly. Other things like barrel length, bullet weight and pressure would be more significant.
As I mentioned before there are some interesting papers on barrel erosion done by the military. Typically they measure barrel life in seconds, and have a pretty good understanding of the mechanisms. (mechanical wear, melting the bore, phase chance in the outer layer (the atoms reaarrange, slightly changing the volume occupied, which causes cracking), and a few other esoteric things.
Long story short, it's my belief that the primary drivers of barrel wear are charge weight, caliber, and barrel time. Charge weight is the total energy, barrel time is how long it has to seep into the bore, and caliber determines the amount of surface area that can soak up the heat (bigger calibers have a lower energy to surface area ratio).
For example, the 30 BR is known for having a long barrel life - big bore, light bullets, shorter barrel, and relatively small charge. A 6.5 x .284 is a known barrel burner - smaller diameter, higher charge, typically heavy bullets. Anecdotally, people seem to get better life out of .308s shooting 155 palma bullets than 200 grain F class bullets (because the heavy bullets increase barrel time).
But like I said before, this is all educated speculation.