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Best Cartridge Designs?

Case geometry is quite important for ignition, and the more powder burning in the barrel will reduce barrel life. A good discussion of this can be found in this patent:

https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7086336

It explains why short fat cases are more efficient and discusses shoulder angle and why some angles work better in some cases. This was developed by a rocket scientist who Designed and studied studied ignition in space shuttle boosters
The trouble with patents is that anyone can make a patent for anything regardless of whether or not it actually works. I remember seeing an old patent somewhere for a silencer that had a trap door on the end to let the bullet out, that would then close and trap the gasses inside. Obviously silly. David Tubb patented his scope reticle that had erroneous ballistic claims. There are many patents like that.

That said, the one you linked is pretty interesting. No idea if he's right, but he certainly seems to have put some work and thought into it. I'll definitely dig into it. What he's saying certainly makes sense in a general sense - that there is a shape that would be more efficient for combustion/ignition. We see that all the time with cases that have different shapes but slightly different velocity potential.

Personally, I *feel* that the short/fat thing as it pertains to accuracy is just an assumption people make because the PPC was such a hit with short range benchresters back int he day when cases like that weren't as common. Now everyone takes it as gospel.

Is there an optimal length/width ratio for cases? Absolutely, for reasons of combustion and igntion as well as practicality (like that patent says). But I've yet to see someone convincingly quantify that in a way that matters for what we do, especially in a way that correlates to accuracy.
 
Draw a line along the shoulder toward the case mouth. If the line is above the case mouth, it will have shorter barrel lid than if line intersected below the case mouth and into the neck wall.
I don't believe this. There is quite a bit of military literature on thraot erosion mechanisms, and none of it mentions this. It's primarily a matter of heat melting the bore and cracking it due to metalurgical changes on the bore's surface due to the temperature.
 
I don't believe this. There is quite a bit of military literature on thraot erosion mechanisms, and none of it mentions this. It's primarily a matter of heat melting the bore and cracking it due to metalurgical changes on the bore's surface due to the temperature.
Where does the heat come from?
 
The trouble with patents is that anyone can make a patent for anything regardless of whether or not it actually works. I remember seeing an old patent somewhere for a silencer that had a trap door on the end to let the bullet out, that would then close and trap the gasses inside. Obviously silly. David Tubb patented his scope reticle that had erroneous ballistic claims. There are many patents like that.

That said, the one you linked is pretty interesting. No idea if he's right, but he certainly seems to have put some work and thought into it. I'll definitely dig into it. What he's saying certainly makes sense in a general sense - that there is a shape that would be more efficient for combustion/ignition. We see that all the time with cases that have different shapes but slightly different velocity potential.

Personally, I *feel* that the short/fat thing as it pertains to accuracy is just an assumption people make because the PPC was such a hit with short range benchresters back int he day when cases like that weren't as common. Now everyone takes it as gospel.

Is there an optimal length/width ratio for cases? Absolutely, for reasons of combustion and igntion as well as practicality (like that patent says). But I've yet to see someone convincingly quantify that in a way that matters for what we do, especially in a way that correlates to accuracy.
As far as pure accuracy goes, I still think the case volume to bullet cross section is the key for extreme accuracy, or prescision.
I believe that the most accurate version of the BR case is the 30BR. Unless you have ever shot one of these, it is difficult to describe just how accurate one of these can be.

I can’t think of any other cartridge that is capable at 100 and 200 yards as the 6PPC, 22PPC short, and the 30BR. The 6PPC seems to have it just right. The 22 PPC doesn’t have it untill you knock the case volume back. The 6BR case does not have it until you finally take it to 30.

Pressure also seems to be a big factor. It is no secret that more than a few 6PPC Shooters are shooting loads that are WAY past what loading manuals list. I really do not know what type of pressures are involved in shooting a 68 grn bullet at 3450 fps out of a PPC sized case, but it would not surprise me to see 70,000 psi. The 22PPC short is the same, pushing 52 grn bullets at 3700 fps.
The 30BR, while not quite as radical, does like pressure. My standard load is my own 112 grn bullet at around 3050.

I have a feeling that if any Factory ever decided to load the 30BR as a SAMMI spec offering, it would not be any where near that.
 
Long neck, step shoulder, short fat body
Yup, THIS ^^^^ to Name, a Few,..
.270 and .300 WSM's, 7 MM SAUM, The 3 Creedmoors and, the 6.5 and 7 PRC's,. ARE all Popular, for a REASON !
AND of course,.. I LOVE my 6 XC !
Gimmee Short, Fattish cases, 30 to 35 Degree shoulders with, Long Necks ( preferably at least, ONE, Caliber, Long ).
This ole' Kid, AIN'T buying, any Rifles or, Barrels, chambered for any,.. Antique, Rifle Cartridges
 
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The trouble with patents is that anyone can make a patent for anything regardless of whether or not it actually works. I remember seeing an old patent somewhere for a silencer that had a trap door on the end to let the bullet out, that would then close and trap the gasses inside. Obviously silly. David Tubb patented his scope reticle that had erroneous ballistic claims. There are many patents like that.

That said, the one you linked is pretty interesting. No idea if he's right, but he certainly seems to have put some work and thought into it. I'll definitely dig into it. What he's saying certainly makes sense in a general sense - that there is a shape that would be more efficient for combustion/ignition. We see that all the time with cases that have different shapes but slightly different velocity potential.

Personally, I *feel* that the short/fat thing as it pertains to accuracy is just an assumption people make because the PPC was such a hit with short range benchresters back int he day when cases like that weren't as common. Now everyone takes it as gospel.

Is there an optimal length/width ratio for cases? Absolutely, for reasons of combustion and igntion as well as practicality (like that patent says). But I've yet to see someone convincingly quantify that in a way that matters for what we do, especially in a way that correlates to accuracy.
There is an equation that predicts the parameters of an “efficient” case - velocity/ grains of powder. Those cases seem to deliver. that case uses a rounded shoulder. The rounded shoulder yields highe velocity than a straight shoulder. What seems to be important is the ratio of neck diameter to body diameter. The limitation to the SMc line is bolt face size for cases larger than 6.5mm bullet. By was a real rocket scientist, and at the time of his death he had developed a coating which applied to the inside of pistol cases improved ignition and increased velocity.
 
The burning powder transfers heat to the bore. I'm not sure what you're getting at. The energy content of the powder has nothing to do with the neck/shoulder configuration.
I am not saying shoulder angle is the ONLY characteristic that affects barrel life. I was just saying that as the powder burns and expands in the case, the shallower angles allow more burn to be in the case. The angle pointing toward the case, means the only heat from case is coming straight out of case mouth instead of straight and directly hitting the side of the throat as it exits.

I would hypothesize, all things being equal a cartridge with a 15* shoulder compared to a 30*, the 30* would have less throat erosion with the same number of rounds fired.

Or maybe it is not the shoulder angle guiding hot gases into neck wall vs barrel throat, but the shallower angle redirects hot gases into the case to burn longer in the case itself vs more escaping case and burning in the barrel - "efficient" cases.

I may be wrong. There are many things that look like they would yield a certain result, but do not. I have not test this theory. I have also not come across others that have tested it either. There have been loose comparison of straight wall cartridges to bottle neck, that is apples to oranges.

Damon, can you explain more why the theory does not work? Asking out of sincere curiosity.
 
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With a deft application of thermodynamics, physics and mathematics, the best cartridge could be designed, if it hasn't already through empirical research.
However, I do appreciate the elegant simplicity of the 45/70.
 
I am not saying shoulder angle is the ONLY characteristic that affects barrel life. I was just saying that as the powder burns and expands in the case, the shallower angles allow more burn to be in the case. The angle pointing toward the case, means the only heat from case is coming straight out of case mouth instead of straight and directly hitting the side of the throat as it exits.

I would hypothesize, all things being equal a cartridge with a 15* shoulder compared to a 30*, the 30* would have less throat erosion with the same number of rounds fired.

Or maybe it is not the shoulder angle guiding hot gases into neck wall vs barrel throat, but the shallower angle redirects hot gases into the case to burn longer in the case itself vs more escaping case and burning in the barrel - "efficient" cases.

I may be wrong. There are many things that look like they would yield a certain result, but do not. I have not test this theory. I have also not come across others that have tested it either. There have been loose comparison of straight wall cartridges to bottle neck, that is apples to oranges.

Damon, can you explain more why the theory does not work? Asking out of sincere curiosity.
First, I don't know the answer. I'm speculating as much as you are. My suspicion is that the angle doesn't matter because within practical limits, the difference to the gas flow would be too small to measure. I'd buy it if the case was silly - like 1" diameter .17 caliber with a 60 degree shoulder. But 30 vs 40 degrees with a normal sized case head and caliber?

Think about barrel time - it's roughly .002 seconds give or take. That's the amount of time that the flame has to transfer heat to the bore. How much of a delay would the shoulder angle really make? I have a hard time believing it's enough to change barrel time significantly. Other things like barrel length, bullet weight and pressure would be more significant.

As I mentioned before there are some interesting papers on barrel erosion done by the military. Typically they measure barrel life in seconds, and have a pretty good understanding of the mechanisms. (mechanical wear, melting the bore, phase chance in the outer layer (the atoms reaarrange, slightly changing the volume occupied, which causes cracking), and a few other esoteric things.

Long story short, it's my belief that the primary drivers of barrel wear are charge weight, caliber, and barrel time. Charge weight is the total energy, barrel time is how long it has to seep into the bore, and caliber determines the amount of surface area that can soak up the heat (bigger calibers have a lower energy to surface area ratio).

For example, the 30 BR is known for having a long barrel life - big bore, light bullets, shorter barrel, and relatively small charge. A 6.5 x .284 is a known barrel burner - smaller diameter, higher charge, typically heavy bullets. Anecdotally, people seem to get better life out of .308s shooting 155 palma bullets than 200 grain F class bullets (because the heavy bullets increase barrel time).

But like I said before, this is all educated speculation.
 
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First, I don't know the answer. I'm speculating as much as you are. My suspicion is that the angle doesn't matter because within practical limits, the difference to the gas flow would be too small to measure. I'd buy it if the case was silly - like 1" diameter .17 caliber with a 60 degree shoulder. But 30 vs 40 degrees with a normal sized case head and caliber?

Think about barrel time - it's roughly .002 seconds give or take. That's the amount of time that the flame has to transfer heat to the bore. How much of a delay would the shoulder angle really make? I have a hard time believing it's enough to change barrel time significantly. Other things like barrel length, bullet weight and pressure would be more significant.

As I mentioned before there are some interesting papers on barrel erosion done by the military. Typically they measure barrel life in seconds, and have a pretty good understanding of the mechanisms. (mechanical wear, melting the bore, phase chance in the outer layer (the atoms reaarrange, slightly changing the volume occupied, which causes cracking), and a few other esoteric things.

Long story short, it's my belief that the primary drivers of barrel wear are charge weight, caliber, and barrel time. Charge weight is the total energy, barrel time is how long it has to seep into the bore, and caliber determines the amount of surface area that can soak up the heat (bigger calibers have a lower energy to surface area ratio).

For example, the 30 BR is known for having a long barrel life - big bore, light bullets, shorter barrel, and relatively small charge. A 6.5 x .284 is a known barrel burner - smaller diameter, higher charge, typically heavy bullets. Anecdotally, people seem to get better life out of .308s shooting 155 palma bullets than 200 grain F class bullets (because the heavy bullets increase barrel time).

But like I said before, this is all educated speculation.
Damon,

As I researched this more, I came across Fred Zigler's article (below). He notes that McPhearson's assertions of less barrel wear need more study, but his overall is that cartridge design doesn't affect velocity or accuracy.

I have not been able to find the military studies barrel erosion and cartridge design you referenced. Can you share those?

Ammo: Does Case Shape Really Matter?
By
Fred Zeglin
-
August 15, 2017
There have been a number of factory and wildcat cartridges that have played with case design. But has it had any real effect on ballistics?
Hot shots about a case design's effects on ballistics:

  • As far back as 1946, gun writers and experts already concluded case shape had no effect on velocity or pressure.
  • No matter how a case is shaped, if it is measured against one of the same caliber and capacity, it will have near identical internal ballistics.
  • Col. G.O. Ashley did a load of range work comparing the .257 Ackley and a wildcat of the same caliber called the .25x60mm C.A. to support the conclusion case shape has little to no effect on ballistic performance.
  • Despite this evidence, there are still wildcatters and manufacturers who claim to have innovative case designs and promise the moon when it comes to performance.
  • Ackley himself acknowledged the limitations of cartridge design, saying: “There is no evidence which substantiates the claim that one cartridge design is more accurate than another.”

As far back as July, 1946, American Rifleman ran an article by C.C. Merideth discussing this very question of case design. His conclusion, “… we must arrive at the conviction that any variation in pressure to velocity ratio ensuing from any alteration in chamber shape is negligible as compared to other purely mechanical changes, such as altering bullet diameter, wear in the throat and many other possible differences between any two apparently identical rifles.”
Bob Hutton knew of the Merideth article mentioned above; he was sure he could disprove the conclusions drawn there almost 20 years earlier. He created a wildcat with the same case capacity as the .219 Donaldson Wasp in a short, fat configuration. Prior to testing, he expected that the design would allow the use of slower burning powders for better overall results. In testing, he found that it required the exact same powder and charge and delivered identical results.
Hutton, while discussing the concept of modern cartridge design (including improved cases), wrote, “Shape, in the mathematics of interior ballistics, makes no difference.” It's important to understand that we are talking about internal ballistics not how the case functions in a given chamber design. The idea is simple and easily demonstrated. If a cartridge holds 40 grains of powder and if all other variables are equal it will produce statistically identical results along with any other design of the same caliber with any shape chamber you can imagine so long as it also holds 40 grains of powder.
Col. G.O. Ashley did an article that required a fair amount of actual range work. He and a couple of gunsmiths used a .257 Ackley Improved and a wildcat called the “.25x60mm C.A.” The idea was to have cartridges of the same caliber and capacity with totally different shapes (the exact discussion we are interested in here). The two cartridges ended up within 1.1 grains water weight capacity, about as close as you could get. These tests showed that the Ackley case delivered between 3 and 12 fps more velocity than the .25x60mm C.A., statistically that is a zero, especially since the 1.1-grain edge in capacity belonged to the Ackley Improved. All this is in support of Hutton’s statement that case shape has no effect on internal ballistics or how the powder is consumed in the process of driving a projectile down the bore.
Most recently, the SMc line of cartridges came to the market. Mic McPherson and By Smalley partnered to create www.superiorballistics.com (a now defunct web site) to promote their ideas. “SMc naming designation accounts for caliber and usable case capacity. For example, our 5/35 SMc is a 20-caliber (5mm) cartridge holding about 35 grains of water (to base of neck). One important patented design characteristic of all SMc cartridges is a powder column that is between about 2 times and about 2.1 times bullet diameter.”
This is the newest design to claim improvements in ballistics via case design. In reading over the data provided on their site no pressure data was provided. Knowing that pressure and velocity are directly correlated you have to assume from the velocities reported for the 5/35 SMc that they are not afraid to load hot. Now to be fair, they are using high quality brass and this probably helps with handling pressure as the cases are relatively thick in the wall and designed for top pressures.
The only new information that this line of cartridges brings to the table is a fairly extensive test of barrel heating. The conclusion of McPherson in a nutshell is that the SMc design produces less barrel heating and possibly less throat damage than other cases tested.
It appears from the data reported that contentions about barrel heating were proved out in McPherson’s tests. He went on to say that the test should be repeated to insure the results were accurate. So, how does this relate to our axiom that case design has no effect on internal ballistics and velocity? I would say that only further testing could determine if the ideas of the SMc really have merit. Nearly thirty years of experience in gunsmithing, reloading, and barrel making tell me that it’s not likely that any increase in velocity is a result of the design in question, but rather a result of hot loads.

So where does the increased velocity come from in an Ackley Improved case design? It’s very simple — more case capacity. Ackley did not merely change the shape of the case. He added, in most cases, a fair amount of case capacity, which allows for more powder while holding the overall pressure to the same limits. This added capacity is only available for increased loading after the cases are fireformed to the chamber.
Customers often ask, “What pressure does that wildcat operate at?” The answer is, exactly the same pressure as the factory counterpart, or parent case.
Ackley thought he could exceed the pressures of the factory cases … that might be true with antiquated designs like the .30-30 WCF or the .25-35. Cases with a lot of taper were often originally held to lower chamber pressures. It is not true of more modern designs that already have relatively straight walled cases and sharp shoulders, also modern cases normally are designed for higher pressures. A good example of a high pressure design is the .270 Winchester, it was one of the first cases to be loaded to full potential by the factory, modern SAAMI specifications show the .270 at 65,000 psi.
The .30-06, which many consider to be modern in design, is limited to 60,000 psi by SAAMI. The factories tend to load .30-06 ammo below that pressure level. Why? Because there are large numbers of older and often weaker rifles in general use, so it is wise of the factories to hold those pressures down.
In the case of the .270 Winchester, it was never available in these weaker actions from the factories, and they do not have to take responsibility for custom guns on old actions, so they load it to full potential. This gives us an insight into the reason that Ackley perceived his .270 AI to be no real improvement over the .270 Winchester.

Once fireformed, a .30-06 AI can be loaded to the full potential of the brass. In a modern high quality action that is at least 60,000 psi, and most wildcatters will go straight for the 65,000 psi as SAAMI uses with the .270 and many other modern cartridges.
If you check the pressure on the average handload in any caliber you will find that it is well above the pressures of factory ammunition. So it’s easy to see why folks think that case shape increases velocity. In reality it is simply more powder and the fact that you are probably loading hotter than the factory.
Ackley should have the final word here. “There are no Wildcat cartridges which are actually revolutionary. There are a few which fill gaps between existing commercial cartridges. There are many more which are no better and perhaps not as good as their commercial counterparts.
“There is no evidence which substantiates the claim that one cartridge design is more accurate than another. It certainly cannot be demonstrated that inaccurate barrels can be made more accurate by simply rechambering them to some so-called ‘improved’ cartridge or Wildcat caliber.”

Editor's Note: This excerpt is from P.O. Ackley: America's Gunsmith available exclusively at GunDigestStore.com.


From <https://gundigest.com/gear-ammo/ammunition/ammo-case-shape-matter>
 
Here are the McPhearson articles - same company that put the previously mentioned patent in.

NOTE: We wrote the following article very early in
the development of what became the patented
and trademarked SMc cartridge design.
As such, we later proved that many things we speculated on in
this article were imprecise. I have included this article
on the web page for historical completeness only.

~~~~~~~~~~~~~~~~
June 2000,
M. L. (Mic)McPherson,
Ballistician;
With contributions from Mr. Robert Byrom Smalley, Jr.,
Rocket Scientist


Co-Titles:
OPTIMIZING CASE SHAPE AND DESIGN
(McPherson);
A ROCKET SCIENTIST’S THOUGHTS ON OPTIMIZING
SHOULDERED-CASE DESIGN
(Smalley)
SYNOPSIS:
Despite more than 150 years of the self-contained cartridge, we have seen precious little documentation covering research into case design optimization. New information — gleaned from the disparate design disciplines of solid-fuel rocket engines and, of all things, 2-Cycle engine exhausts — suggests that a relatively short, fat case with a specific shoulder design may very well be ideal.

Owing to the difficult nature of this subject, I have erred toward too much detail; therefore, the following article contains a measure of deliberate repetition. Please note, that as the primary author, I (M.L. McPherson) must take responsibility for this text, while Mr. Smalley and I have worked together in an effort to fairly represent this subject, we do not necessarily fully agree on the importance or accuracy of every aspect discussed in the following text. Furthermore, I am happy to take full responsibility for any errors, conceptual, factual, or otherwise. Finally, please, bear in mind that our goal is only to present the details of a basic argument.
Mr. Smalley (who prefers the moniker,
By) retired as a principal engineer in solid rocket engine design, a field with definite relationships to cartridge design. As a hobbyist, he participated in the design of several World Record holding model airplane engines. Specializing particularly in exhaust system design, By designed and optimized an exhaust system based upon an idea originated in the late 1800s. He thereby helped design a 0.049 cubic inches, 2-Cycle engine with world-beating size- and weight-to-horsepower ratios, which propelled a scale airplane to 120 mph! Later, we will see the surprising relationship that work has to one aspect of optimizing cartridge design.
I am not shy about theorizing; sometimes that is good. My recent forays into the discussion of case design seem to have been of that ilk. Regarding my speculation on, ultimate case design, I have heard from my friend, Bob Bell (respected, long-time Handloader’s Digest Editor), many PS readers, two reamer manufacturers, one gun manufacturer and now a genuine rocket scientist, Mr. Robert Byrom Smalley, Jr.
Numerous responses from various Precision Shooting readers suggest that this subject is of general interest. In his letter, Mr. Bell noted that a half-century ago, “There was considerable debate among shooters along these same lines.” He kindly added that such debate was “… without any firm direction or any comments showing the advanced thinking that your articles suggest.” He goes on to offer evidence that, for most shooters, the entire issue amounts to much ado about almost nothing — existing designs are so good (emphasis, mine). Nevertheless, I would contend that better is better and progress toward that unobtainable goal perfection is at the heart of the pursuit of Extreme Rifle Accuracy.
During various telephone conversations, By, confirmed that I am on the right track. While an overall optimum case design may not exist, it is possible, at least in theory, to optimize case design for any particular set of components and cartridge performance level. Critical variables include: powder column length-to-diameter ratio, case shoulder angle, bullet mass compared to cross sectional area, bullet base configuration (boattail versus flat base, etc.), effective friction load (neck and barrel), seating depth, case filling ratio and ratio of case volume to bore cross-sectional area. Generally, such a design will represent a unique accommodation to three factors: first, minimization of interior surface area; second, minimization of distance from initiating primer blast to furthest powder granules; third, a suite of shoulder design considerations, which have several critical influences.
Military small arms and artillery designers have some incentive to produce the most efficient case shape. However, that research information is not readily available and, after all (excepting a few weight-critical applications, such as helicopter armament), adding a bit of steel to a gun or material to a cartridge case or powder to a propellant charge is of little relative importance. Furthermore, for most applications, cartridge design must also accommodate handling and chambering considerations.
On the other hand, in rocketry, weight considerations dominate — with current technology, it can cost $20,000 to place one pound of anything into orbit and, critically, every pound added to the engine results in a significant payload loss. In other words, in rocketry, designers have the ultimate incentive to design the most efficient (lightest) engine possible. Those pushing the envelope of cartridge design have precisely the opposite motivation; for them, cost (weight) is not an issue — only results matter.
While considerably more energetic, solid rocket fuel is, for practical purposes, significantly similar to conventional smokeless powder. Furthermore, criteria for designing the most efficient solid rocket engine turn out to be germane to the issue of designing the most efficient and ballistically consistent cartridge case. Before making any general conclusions, and without entering into boring detail, I would like to review this subject and visit a few facts from various discussions between By and me.

BACKGROUND, CLARIFICATION AND A BIT OF REVIEW
The primer blast does several things to the powder charge. First, it drives the base of the charge forward and it can also create an axial hole to some depth. Second, it directly ignites some granules, either by condensation heating (as nascent combustion gases condense onto surfaces) or through contact heating (as incandescent particulates penetrate surfaces). Third, through compressive shock, it can significantly heat granules that do not ignite. Fourth, it can partially fluidize unignited granules, causing some degree of granule-to-granule fusing — this significantly changes the nature of individual granules and the propellant mass.
ADIABATIC HEATING
While compressive (shock) heating probably does not lead to direct granule ignition, in some cartridges, it is of significant importance because, by raising granule temperature, it can dramatically reduce ignition delay — when those granules are subsequently further heated by the producing energetic propellant cloud.
Also, during the combustion phase, adiabatic heating of air within the charge mass can significantly heat adjacent surfaces. This heating occurs as initially unignited granules deform plastically. First the smaller openings are sealed, which eliminates porosity. Then gas in the remaining voids is further compressed. As confining pressure increases, void volume shrinks and temperature increases.
Under some circumstances, these pockets might be large enough and become hot enough to heat adjacent granule surfaces sufficiently to cause ignition. This potentiality is particularly noteworthy in those combinations where the case is not filled with powder. There, granule heating through primer-blast-related compressive forces can be significant. This is almost certainly a factor in reduced-charge detonations with slow powders. Indirect and lesser effects of this phenomenon could also explain why the most accurate loads seldom use significantly less than a case-full charge.

KINDLING VERSUS IGNITION
Here I must clarify a significant detail. Some readers may not recognize the important distinction between kindling point and ignition point. For this discussion, we can consider kindling point as that temperature where smokeless powder ignites in response to very slow heating — the temperature gradient in the near-surface layers is very modest. Conversely, ignition point is that temperature where smokeless powder ignites in response to very rapid heating — the temperature gradient in the near-surface layers is significant. This distinction is critical, particularly when discussing late-stage ignition — where granules escaped ignition either from the primer blast or through the action of developing propellant gases until after the bullet began to accelerate.
Kindling point is also known as Thermal Decomposition Point. This is defined as that temperature where more heat is generated by decomposing propellant surface layers than is conducted into the propellant (exothermal reaction). Subsequently, in order to maintain granule surface temperature, it becomes necessary to remove heat.
Ignition Point depends upon heating rate because the faster that heating occurs, the hotter the surface layer can get before the temperature gradient in the surface layers exceeds the rate of thermal conductivity between those layers. Consider heating to any specific surface temperature: when heating occurs slowly, the heated zone gets relatively thick, so that underlying cooler layers cannot rapidly wick away additional heat; when heating occurs rapidly, the heated zone stays relatively thin, so that underlying, cooler, layers can rapidly wick away additional heat.
Kindling (thermal decomposition) point for various typical smokeless propellants is listed as a surprisingly mild 160-170 degrees C (320-338 degrees F). This reflects the temperature of slowly heated surrounding air when a sample spontaneously ignites (exothermal reaction ensues), during very slow laboratory heating. Such ignition is completely unlike what happens in a cartridge. There, condensation of primer gases onto granule surfaces results in extremely rapid heating. In this instance, if we could measure granule surface temperature at the instant of ignition, we would find that it was far higher than the laboratory-derived thermal decomposition point. A demonstration that ignition point depends upon heating rate.
This analysis applies to those granules not ignited by the primer. While the various forces involved in the ignition phase and during nascent propellant combustion typically generate granule surface temperatures far exceeding the thermal decomposition point (up to 2650 degrees C — 4800 degrees F), such granule surface heating occurs extremely rapidly; therefore, ignition temperature is a function of ignition point, not kindling point. Furthermore, once powder gases generate sufficient force to begin to move the bullet, any unignited granule typically has far less than 2 milliseconds (2/1000 seconds) to achieve combustion before the bullet reaches the muzzle. The bottom line, it is quite common for such granules to entirely escape ignition. Anyone who does not believe this happens should talk to those folks who have watched an indoor shooting range burn to the ground because of incautious cleanliness practices that allowed too much unburned propellant to build up — Hodgdon almost lost its range this way and Nosler lost much of its entire testing facility, dozens of commercial indoor ranges have succumbed to this.

CARTRIDGE EFFICIENCY AND CONSISTENCY
The goal of any cartridge is to convert potential chemical energy of powder granules into kinetic bullet energy. Therein, granules that do not ignite before the bullet begins to move suffer four progressive deficits. First, produced gases have less time to work on the bullet — which is moving faster and getting closer to the muzzle. Second, as bullet velocity increases, propellant push weakens — both molecular velocity and gas flow velocity through a bore are limited. Third, compared to underlying layers, energy production from deterred surface layers is lower. Fourth, as bullet movement exceeds a few inches, confining pressure decreases dramatically, so combustion occurs at a much slower rate.
Consider an example: 308 Winchester, 150-grain bullet, 50-grain charge. If a 10-grain plug of unignited powder follows the bullet into the bore, then initially, the effective bullet is 160 grains and the effective charge is 40 grains. Unless granules in this plug can ignite soon enough and burn fast enough to pressurize the developing void behind the accelerating bullet, that plug not only does not add to performance but its acceleration absorbs energy that could otherwise accelerate the bullet.
For these reasons, as the bullet progresses through the bore, energy conversion efficiency for newly ignited granules plummets. This reduction is dramatically non-linear. Compared to granules that ignite before the bullet begins to move: typically, the combustion of granules igniting after the bullet has traveled one-fourth the distance to the muzzle contributes much, much less than one-half as much projectile energy per grain of propellant gas produced; granules escaping ignition until after the bullet moves halfway to the muzzle are unlikely to ignite and, even when ignition occurs, contribute essentially nothing.
As an example, consider a typical 308 Winchester load using VarGet and the 168-grain MK bullet. In that combination, once bullet movement begins, it takes only about 0.582 milliseconds for the bullet to move 5 inches (one-fourth total travel distance for that bullet in a 21.591-inch barrel, beginning with an overall cartridge length of 2.8-inches), see graph.
Thereafter, any newly unignited granule has only about 0.540 milliseconds to contribute to bullet energy (1.122 ms – 0.0582 ms = 0.540 ms), see graph.
Equally, the purpose of any accuracy-critical cartridge is to produce the most consistent possible ballistics. Everything in the following text is predicated upon understanding that ballistic uniformity is enhanced by early (consistent) granule ignition and, conversely, ballistic uniformity is degraded by late (typically inconsistent) granule ignition (and low loading density). Briefly, increasing the delay between the primer blast and individual granule ignition increases the resulting ballistic effect of minor variations in that delay — the ideal is achieved when all granules ignite before the bullet begins to move. Refer to my earlier articles, The 6mm Shortly and Bringing the Short Fat Case to 1000-Yard Competition (Precision Shooting Publications).

CORRESPONDENCES AND DISTINCTIONS BETWEEN
CARTRIDGES AND SOLID-FUEL ROCKET ENGINES

Now, some facts, and a bit of conjecture about comparisons between solid-fuel rocket engines and cartridge cases. First, propellant granules differ dramatically. Typical rocket engines use no more than a few granules (called grains), which are typically designed to burn one at a time, with constant energy production, and thereby to maintain constant chamber pressure as produced gases jet through the exhaust orifice, with the only significant impediment being the nozzle throat; typical cartridges use many hundreds to many thousands of granules which, as demonstrated above, produce best performance when all have ignited before the bullet begins to move and which are designed to push against a relatively heavy exhaust (bore) impediment (the bullet) and where practical barrel length is limited.
These factors lead to dramatic differences in burn times and pressures — rocket engine burns typically last many seconds and generate pressures of several hundred to several thousand psi — small arms cartridge burns typically last less than 0.002 seconds and generate breech face pressures that can exceed 75,000 psi. However, I see a more important distinction.
In a rocket engine, trapped air pockets can be devastating. There, such pockets often result in secondary ignitions that multiply total combustion area and thereby catastrophically skyrocket chamber pressure — remember all those spectacularly explosive failures in the early US space program?
In the cartridge, trapped-air pockets are unavoidable but are also relatively tiny, except, perhaps, in a partially filled case. At issue is a factor related to latent heat of compression, which manifests as a compression-related temperature increase within interstitial voids — as volume shrinks, gas molecules move faster (temperature increases). Compression of pockets, large or small, to any given pressure generates the same pocket temperature. In rocket engines and cartridges alike, pocket temperature often exceeds the kindling point temperature. However, total heat depends upon pocket volume.
Critically, it takes both heat and temperature to achieve ignition in adjacent granule surfaces. As heat is transferred from the hot gas to the cool granule, the gas cools. If the pocket is too small, it simply will not contain enough energy to heat adjacent surfaces sufficiently to cause ignition, despite the extremely high temperatures that can occur within the compressed gas voids. By and I contend that such heating occurs so rapidly that although an exothermic reaction could be initiated in the surface layer, the underlying cool layers will quench the reaction before sufficient additional heating can occur to result in a sustained reaction — as was discussed above. (Precision Shooting’s resident Rocket Scientist, Randolph Constantine, also points out that much or all of the heat in such voids could be dissipated in the endothermic — heat absorbing — decomposition of the adsorbed anti-oxidants in the surface layers.)
Thus, in a normal cartridge load, the myriad, relatively tiny, gas pockets seem unlikely to cause secondary ignitions. However, it is quite certain that this effect will expedite subsequent granule ignition. When those pre-heated surfaces are finally exposed to the combusting propellant cloud, hotter areas will ignite faster, which is a critical factor. My point here: Owing to issues of scale, not all rocket-to-cartridge comparisons are equally applicable but the basic concepts do cross over.
A second point By stressed was that dramatic powder granule compression, which occurs when a cartridge fires, results in granule fluidization. Individual particles fuse and reconfigure. Within microseconds the myriad granules become a single mass of viscous fluid. As granule surfaces begin to fuse (at least temporarily), interstitial gas pockets become isolated and essentially spherical. For this reason, further ignition results only at exposed surfaces or where granule-to-granule shearing occurs. Inter-granule shearing can open up new paths for propellant gases — we will return to this point.
Owing to adsorbed surface chemicals (which affect both physical and chemical granule characteristics) and size and separation of gas pockets, subsequent burning rate still reflects initial granule characteristics. Critically, individual granules retain the progressive burning gradients imposed by the deterrents. Further, these granules are not necessarily inseparable.
Pressure of a few thousand psi (far below peak chamber pressure) dramatically deforms unignited granules, which are generally located in continuous masses. (My testing demonstrated that a relatively mild pressure of 3000-psi compresses typical tubular and ball powders about 10%, which implies significant deformation.) For this reason, those granules escaping initial (primer blast) ignition show little difference in performance, whether stick- or ball-type.
Regardless of any such details, my pertinent points from the original articles stand (to which, please refer), ideal case designs: 1) minimize interior surface area, and 2) maximize granule-mixing rate at the shoulder-to-neck transition. By, who believes it is of significant importance, reiterated a third point 3) minimizing distance between the primer flash and the remotest granules. By also points out that we have to add a new dimension to this theorem 4) maximizing primer-blast related heating of those granules in the bore-diameter column, directly behind the bullet — which contains powder that can follow the bullet into the bore as an unignited plug. (Again, refer to the aforementioned articles for background.) See sketches 1a and 1b.
In the following text, we assume that chambering characteristics provide for the base of the bullet shank to precisely align with the neck-to-shoulder junction of the case.

  • MINIMIZING INTERIOR CASE SURFACE AREA
This aspect is critical because it minimizes conversion of primer blast heat into case heat, and for several other reasons. If this were the only consideration, the answer would be quite simple — design a spherical combustion chamber. This is certainly feasible but it will require a new case, drawn with new tooling. Meanwhile, because that basic shape cannot be achieved with a conventional cartridge, we will consider conventional (cylindrical) designs. Here, in the ideal design, powder column diameter equals length.
However, unless someone wants to dramatically shorten a 50 BMG or neck a similarly shortened 416 Rigby to 17-caliber (have fun!), we are in no danger of designing a full-power case that is shorter than it is wide. Therefore, we can say that we should use the fattest case feasible.
(It is noteworthy that progressively fatter cases require progressively fatter actions and that such designs impose increasing levels of axial stress and primer-blast-derived shock — and vibration — into the barrel, characteristics that are probably detrimental but which we will not address further here.)

  • MAXIMIZING GRANULE MIXING RATE AT THE SHOULDER-TO-NECK JUNCTION
Consider granules trapped behind the case shoulder and not directly ignited by the primer. Chamber pressure rapidly compresses this mass and thereby eliminates permeability.
Thereafter, hot propellant gases cannot penetrate and, therefore, granule ignition occurs only at exposed surfaces. Separation of surface granules exposes new material, which can then ignite. Shearing forces and convection enhance this process.
As the bullet accelerates, the unignited mass is sheared where a bore-diameter plug begins to follow the bullet into the bore. See Sketches 1a and 1c. By contends that this shearing action is sufficient to allow ignition to progress along the sheared zone, at least where both surfaces are composed of exposed powder. However, it has been demonstrated that ignition does not occur along the perimeter of this plug where it is moving through the case mouth or the bore (evidently those relatively cold surfaces prevent sufficient powder heating). Therefore, we can predict that most of the time there will be some portion of this plug that is not ignited along the perimeter and will, therefore, burn only from the base forward.
Convection force on the viscous fluid mass that is trapped behind the shoulder is significant only at the shoulder-to-neck junction. There, the mass is exposed to the propellant cloud jet that is rushing through the neck as the bullet accelerates. Resulting strain depends upon pressure loss in the wake of the accelerating bullet.
With regard to minimizing granule transport time from the case perimeter (where the remotest unignited granules are located) to the neck opening (where ignition will occur), geometric arguments suggest that an ideal conventional shoulder angle exists — all other things being equal, I believe this angle should be 45-degrees. With a milder shoulder (e.g., 30-degrees), granules proceed faster but must travel so much further that travel time is increased; with a steeper shoulder (e.g., 60-degrees), granules have a shorter path but must proceed so much slower that travel time is increased.
Endpoint analysis supports these conclusions — as the shoulder angle approaches zero-degrees, granule travel distance to the shoulder-to-neck junction increases without bound; equally, as shoulder angle approaches 90-degrees, granule flow rate approaches zero. Evidently, the magic angle is 45 degrees, where flow rate and travel distance yield the fastest straight-line path.
On the other hand, a steeper shoulder increases divergence of clump velocity and propellant jet velocity at the shoulder-to-neck transition; this increases convection and thereby speeds granule separation and subsequent ignition. Shallower shoulders produce progressively less convection, as granule clump velocity approaches propellant jet velocity.
Also noteworthy is that at relatively shallow shoulder angles, shoulder-to-neck junction convection essentially disappears. At some point, the entire fluid mass simply swages to bore diameter, following the bullet as an elongated lump. Logically, the rearward portion of this lump would be ignited along the axis but a significant portion toward the front could well enter the bore unignited.
I believe sound geometric arguments will suggest that optimization of both convection and feed rate occurs with a shoulder angle of 60-degrees, which just happens to be near the angle of repose for smokeless powder. This angle provides significant convection while still allowing flow to proceed with reasonable dispatch.
Which of these characteristics (perimeter-to-neck transport rate versus convection strength) dominates, very likely depends upon several factors, two of which seem particularly important: geometry of powder volume escaping initial ignition, and bullet acceleration rate. Nevertheless, regardless of specific details, from this single perspective, ideal shoulder angle is evidently comparatively steep, almost certainly >45-degrees.

  • MINIMIZING DISTANCE BETWEEN EFFECTIVE PRIMER BLAST IGNITION ZONE AND THE REMOTEST PROPELLANT GRANULES
Here By and I agreed that we do not have sufficient information to settle a significant point of contention. Does the primer produce a jet that tends to ignite the powder column from the axis toward the perimeter, which By believes might be an important mode; or, does the blast tend to force the charge base forward while rapidly spreading to full case diameter, and thereafter ignite the powder column from the base forward, which I believe is the dominate mode. We agree that reality is probably somewhere in the middle.
Perhaps surprisingly, regardless of actual ignition mode, minimizing the distance between the primer blast and the remotest granule in a cylindrical column requires the same shape — column diameter is twice column length. See sketches 2a and 2b.
What seems a more realistic representation of reality follows: As the primer blast penetrates into the powder column, proceeding from the base toward the shoulder, the leading edge rapidly extends to full case diameter, while developing a roughly hemispherical face. Refer to photograph of unconfined primer flash and sketch 3.
Regardless of specific details of actual ignition — which seem almost certain to vary, depending upon powder type, charge density, primer type, total case volume, flash hole configuration, and several other factors — it seems evident that in this regard, a short, fat case provides a significant advantage.

  • MAXIMIZING INITIAL HEATING IN POWDER COLUMN DIRECTLY BEHIND BULLET
To understand the importance of this point, we must first realize that any granules in the column directly behind the bullet that do not ignite before the bullet begins to move will thereafter simply follow the bullet into the bore as part of a single clump. Thereafter, ignition of the forward portion of this clump is likely to occur only at the base. This means a good percentage of these granules will escape ignition for a relatively long time (and until the bullet has proceeded far into the bore). Equally, we must recognize that anything resulting in increased granule preheating will reduce subsequent ignition delay.
The importance of this factor likely depends upon what percentage of the total charge is included in this zone. Here, the shorter, fatter case excels because, for an equal case volume and caliber, this column will be shorter and contain a smaller percentage of the total charge. Compare sketches 1a and 1c.
The pertinent point is that a primer-generated shock wave travels through the powder column, ahead of the flame propagation front. As noted above, this energetic wave compresses air in interstitial spaces while compressing and deforming granules. Details of this shock wave propagation are of little importance to this analysis. The critical point is what happens as that shock wave reaches the case shoulder, where some portion is reflected. With regard to early ignition of granules in the column behind and adjacent to the bullet base (which are those that can enter the barrel as an unignited mass), location and size of the zone where these reflected waves subsequently focus is critical.
Analysis of pressure wave propagation in cylindrical columns, which relates to a similar analysis By did when he designed a World Record setting 2-Cycle engine exhaust, is not trivial. I will gladly abstain from trying to present anything resembling a rigorous discussion; rather, I will simply report what By calculated.
First, at a shoulder angle near 60-degrees, reflected shock wave energy from the case shoulder is directed back, toward the primer. See sketch 4. Therefore, essentially zero reinforcement of primary shock wave induced heating occurs where it is needed. Equally, at a shoulder angle of about 30-degrees, reflected shock wave energy from the case shoulder is directed toward the central powder column, near the bullet base, where it focuses and generates significant reinforcement of primary shock wave heating, thereby bringing about faster subsequent ignition of this ballistic-consistency-critical mass. See sketch 5.
Shoulder designs with angles shallower than 30-degrees seem to be of little benefit in this regard. Moreover, such designs focus more energy on the bullet base and therefore increase the likelihood that the primer blast will dislodge the bullet, which is detrimental. Angles steeper than 30-degrees seem to be progressively less beneficial, owing chiefly to lack of proper focusing but also owing to an increase in the magnitude of axial shock delivered to the barrel through the chamber shoulder, which is also detrimental.

SHOCK WAVE VELOCITY IN A POWDER COLUMN
The primer blast generates a sonic shock wave. This wave moves through the powder column in a complicated manner — depending upon column diameter, column air density, powder granule solid density and elasticity and almost certainly the manner in which granules interact with each other, interstitial air and the case walls. (Shock wave velocity has been precisely measured in specific applications; however, that information is hard to obtain.)
We can, however, make certain reasonable assumptions and predict a velocity of about 1800 fps. This suggests that in the 308 Winchester, shock wave arrival at the case shoulder occurs about 0.069 milliseconds after production from the flash hole. The reflected shock wave focuses at the center of the powder column behind the bullet by about 0.072 milliseconds — long before generated propellant gas pressure is sufficient to begin to move the bullet.
As this primer-blast shock wave travels through the powder column, both air and powder granules are compressed. As this pressure wave passes, granules are fluidized and the entire affected volume can obtain a consistency similar to bread dough. Typically, as this wave passes, developing propellant gas pressure, which travels through the compressed column faster than the initial shock wave travels through the undisturbed column, immediately reinforces the pressure, thereby maintaining granule fluidization.
In response to compression and fluidization, granules obtain a new shape and a greater packing density. Thereafter, very rapidly, those granules can ignite and propellant pressure will become sufficient to move the bullet. As noted, whether a granule ignites before or after the bullet begins to move is the critical point.

A BETTER IDEA, MAYBE
I was quite pleased when we applied the above noted considerations to the 6mm Thermos Bottle, with its essentially maximized body-to-shoulder radius. This design interacts in each of the above four areas as follows:

  1. It is trivial to prove that for a conventional cylindrical case body and for any given volume and diameter, this shoulder design provides minimum possible interior case area.
  2. It is reasonably simple to demonstrate that, so long as neck diameter is not significantly larger than or smaller than one-half of case body diameter, this design approximately maximizes both granule flow rate and convection at the shoulder-to-neck junction.
  3. If initial primer blast penetration into the powder column is similar to what I have hypothesized (see sketch 3), this design also minimizes distance between effective flash front and remotest powder granules.
  4. This design does a splendid job of focusing primer shock wave energy where that is needed (see sketch 6), as explained in the following discussion.
A final consideration in favor of the Thermos Bottle shoulder design relates to the shock impingement of the primer blast upon the case shoulder. Here, as opposed to what happens with a conventional shoulder, a shock wave striking near the perimeter is deflected very slightly and then reflects again and again until it reaches either the powder column directly behind the bullet or the boattail bullet base (where it strikes at a high angle so that it is reflected back into what will become the trapped powder mass behind the case shoulder, which is also beneficial).
Similarly, looking at the next shoulder increment (the radial zone just closer to the neck), that parcel is initially reflected at a slightly greater angle and therefore ends up, on average, focusing into the powder slightly behind the zone where the first parcel impinged; significantly, this parcel will contain somewhat less energy, compared to the previous parcel. This process continues so that this energy is well distributed into the column of powder behind the bullet — just where it is needed and with surprisingly good distribution. See Sketch 6. Importantly, while this is happening, shock energy transfer into the barrel is spread out in time, which is also beneficial because it should result in milder vibrational excitation.

ADDITIONAL THOUGHTS FROM BY
Extremely special case body and shoulder designs could have merit. Among the myriad possibilities are: parabolic configurations (with no distinction between body and shoulder) and elliptical and hemispherical shoulder designs. While interesting, parabolic and elliptical designs could tend to focus the reflected primer blast too tightly, so the hemispheric (or possibly a parabolic) design seems most interesting to me (see sketch 6).
Powder column width-to-diameter ratio is an important consideration when using a conventional shoulder. By believes the proper mix of the above-discussed characteristics leads to a design where interior diameter is about twice bullet diameter and shoulder angle is near 30 degrees for small capacity applications (shorter cases) and near 40 degrees for large capacity applications (longer cases) — he agrees that the hemispherical design may well be a superior choice. We are both impressed that, through trial and error, Ackley seems to have gotten the shoulder angle quite right for hunting cartridges and the target fraternity seems also to have managed quite well — such subsequent proof of empirical results is not unusual. Formerly, it was difficult to find cartridge cases with sufficient body diameter to meet By’s proposed twice bullet diameter criteria. At least for the smaller sporting calibers, this is no longer true. Therefore, new short fat designs should become more and more popular for this and other reasons.
Two other points By felt very strongly about are: 1) bullet mass will influence ideal shoulder angle — a least with a conventional shoulder design — and 2) bullet base configuration might also influence ideal shoulder angle. I might add that effective bullet mass, as influenced by bullet specific characteristics (core and jacket materials, etc.), neck tension, crimp, friction proofing and bullet-to-rifling jump, which will all influence how fast the bullet initially accelerates, is also an important consideration

PRELIMINARY CONCLUSIONS
If the above analysis has merit, it seems evident that there is no such thing as a universally ideal conventional shoulder angle. As noted previously, each powder column length-to-width ratio, each effective bullet mass and each case volume favors a unique angle; this angle depends upon which of the above discussed effects dominates in that particular system. On the other hand, if the Thermos Bottle design works in the manner this analysis suggests, then that basic design might work extremely well across a wide range.
Before closing, I must note that I have been told that, early on in PPC experimentation, a design with a large body-to-shoulder radius was tested; that particular combination proved to generate excessive case stretching, owing (I presume) to lack of adequate headspace control. If that is a general characteristic of such a design, I can only hope that cases with a wider shoulder will mitigate the effect sufficiently to be useful. Time will tell that tale.







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EFFICIENCY: WHY CASE SHAPE MATTERS
M.L. (Mic) McPherson, June 2005
SYNOPSIS: While this has taken more than 150 years, today’s shooters can now begin to realize the benefits of cartridges that are designed for maximum efficiency. These advantages include increased barrel life, superior accuracy, reduced felt recoil, and reduced barrel heating. Because, in hindsight, the reasons that case design matters are easily understood, the question becomes: “Why did this take so long to figure out?”
Let us consider a conventional sporting, centerfire cartridge. Experienced shooters know instinctively that, for any given bore size, a larger case accelerates any given bullet to greater muzzle velocity. Similarly, it is obvious that, all else being equal, loading to increased pressure results in greater muzzle velocity. However, overall cartridge efficiency is hidden in the details of case shape.
SEQUENCE OF EVENTS WHEN A CARTRIDGE FIRES
What may not be so obvious is what actually happens when a cartridge fires. Here we will review a somewhat simplified version of events that occur after the firing pin strikes the primer.
First, the primer explodes. The pyrotechnic primer pellet burns very rapidly, releasing hot gasses and particles. These still-reacting components stream through the flash hole and into the combustion chamber and thereby ignite propellant granules that happen to be located near the flash hole. Testing has proven that the primer does not directly ignite propellant granules that are more than about one-half inch forward of the flash hole.
Simultaneously, as granules begin to burn, the entire charge is compressed toward the front of the case, behind the case shoulder (if any) and bullet. This compression results from two factors: first, the primer shock wave hammers into the base of the charge and thereby transfers momentum; second, gas generated by inchoate propellant combustion and continuing primer pellet combustion generates gas pressure, which is biased near the flash hole. First, the bullet creates a gas seal at the front of the case. Second, while the charge is initially porous and permeable to gas flow, such flow is retarded because the conduits are tiny and convoluted — with the entire combustion event completing within about 1/500-second; gas pressure simply does not have time to equalize throughout the charge.
Therefore, as burning generates more gas, pressure is progressively biased toward the charge base; hence, the unignited propellant mass progressively compresses, thereby plastically deforming the granules. This is a self-supporting reaction, the greater the compression, the harder it becomes for gas to pass into the charge (conduits become ever tinier and ever more convoluted) so that, very soon, the unignited mass is essentially impervious to further gas infiltration. Thereafter, no significant amount of additional hot gasses can infiltrate into the unignited mass; subsequently, ignition and combustion can only occur at exposed surfaces. Even while gas can penetrate, because the front of the case is essentially perfectly sealed by the bullet the penetrating hot gas cannot carry sufficient heat energy into the unignited charge mass to result in ignition beyond the first quarter-inch, or less, of the mass that was not directly ignited by the primer. Normally, in most rifle loads, no bullet movement has occurred while this is happening.

CYLINDRICAL VERSUS BOTTLENECKED
Compare the 308 Winchester and the 45-70 Springfield. In each, the primer will ignite about one-third of the total charge. Before compression can seal off the rest of the charge, secondary ignition into the rearward surface of the unignited mass will penetrate sufficiently so that, perhaps, another one-sixth of the initial total will ignite. Hence, about one-half of the charge will be ignited; the remainder will be a more-or-less solid chunk that is burning only on the rearward face.
As chamber pressure continues to build, pressure acting through the unignited propellant chunk eventually becomes sufficient to begin to force the bullet into the bore. To do so, in the 45-70 Springfield, all that is required is that the total force on the bullet base (force on the base of the unignited mass minus friction between that mass and the case wall) exceeds the force required to push the bullet out of the case.
Conversely, in the 308 Winchester, the perimeter of the charge is trapped behind the case shoulder. Therefore, pressure must built up sufficiently to shear a plug through the trapped propellant mass. When this happens, it creates a propellant plug of approximately bullet diameter. Line-of-sight ignition occurs along the perimeter of this plug and along the interior surface of the cylinder of trapped propellant behind the case shoulder. Ignition along these surfaces significantly increases the total area of exposed propellant with the surface burning, compared to the 45-70 (where the entire mass simply accelerates into the bore, while burning only along the rearward face). Therefore, overall ignition rate is significantly increased. Contrary to intuition, this is the main reason bottlenecked cases require the use of slower burning propellants, when compared to cylindrical cases with a propellant chamber of similar length and when shooting bullets of similar length.

RECOIL IS A FUNCTION OF MASS AND ACCELERATION RATE
It is demonstrated that, at least initially, in the 45-70 a considerable amount of propellant accelerates into the bore behind the bullet. In a typical loading, this could amount to about 30 grains. Conversely, in the 308, the propellant plug would contain about 10 grains. Equally, energy consumed by accelerating solid propellant cannot contribute to bullet acceleration; hence, case designs that accelerate less solid propellant into the bore accelerate bullets more efficiently.
An understanding of the above will help one realize why case design matters. For example, consider a very fat and very short 30-caliber bottlenecked case. No such case is readily available but we could certainly create a case that held just as much propellant as the 308 Winchester but with a propellant column only about one-half inch long. In such a cartridge, primer ignition will reach the bullet base. In this instance, as pressure becomes sufficient to dislodge the bullet, no solid propellant plug will follow the bullet into the bore. All else being equal, the accelerating mass will be minimized.
This means that the gun will initially accelerate more slowly into the shooter’s shoulder — less felt recoil; less total work will be done on the barrel — less barrel heating and wear; and more work will be done on the bullet — more velocity! Any shooter who has done a side-by-side comparison of otherwise nominally identical guns chambered in 300 Win Mag and 300 WSM, will agree that the shorter case generates less felt recoil, despite essentially identical ballistics. This is explained by the fact that the 300 WSM accelerates far less unburned propellant into the bore. (We are not breaking Newton’s law here: total recoil may be similar but the initial rearward gun acceleration will be slower and that is what the shooter is most sensitive to.)
Hence, in general, when considering identical usable case capacities, bottlenecked cases are vastly more efficient than cylindrical cases and progressively shorter bottlenecked cases are progressively more efficient. Modern designs are simply getting closer to the ideal, where the case body is sufficiently short so that very little unignited propellant follows bullet into bore.

BARREL LIFE CONSIDERATIONS
A complication exists regarding barrel life. Consider the 243 Winchester and 6mm Remington. The 243 has about 4% less usable case capacity. It also works at a slightly lower pressure. Shoulder angle is also slightly steeper. Each of these characteristics is recognized as being beneficial toward increasing barrel life. However, the 243 case neck is significantly shorter, which evidently makes all the difference.
Ballisticians have long recognized two significant things when comparing these cases. First, the 6mm is always well behaved — no surprises; conversely, the 243 is notorious for generating unexpected results, including unexplained pressure spikes. Second, inexplicably, the 6mm offers significantly greater barrel life, some have reported a 2:1 advantage!
The only reasonable explanation for the latter fact (which may also explain the former quandary) is that the long neck of the 6mm somehow protects the barrel throat. I believe this is precisely the situation. I suspect that a long case neck saps heat out of the perimeter of the propellant plug (as that plug begins to push the bullet into the bore). If the case neck is long enough, the cool brass can extract enough heat from the plug to quench the burning, at least along the front end. In this instance, a significant length of unignited propellant follows the bullet into the leade (beginning of rifling). This would allow the steel at the bore interior to cool slightly, after being heated dramatically by deformation and friction during bullet passage, before it is assailed by the full brunt of the subsequently passing incandescent propellant gasses.
Conversely, in the 243, the short case neck cannot cool the plug surface sufficiently to quench burning along the perimeter; hence, as the plug passes into the barrel, the exterior is burning. This further heats and corrosively damages the steel. If true, occasional variations in how the plug perimeter continues to burn could explain the pressure spikes and general difficulties that ballisticians routinely report with the 243.
Brass absorbs heat 400 times faster than smokeless powder and several times faster than steel, so cool brass is very effective at delaying the ignition and burning of smokeless powder — cold brass can even extinguish contacting granule surfaces that are already beginning to burn!
Whatever the explanation, longer case necks appear to be useful. I believe these add to barrel life because such a design allows for a short protective plug of unignited propellant to follow the bullet. If this is true, then not only is a long case neck desirable but we also do not want the case to be too short, else no plug would exist.

OPTIMUM DESIGN
My partner, By Smalley, and I (Superior ballistics Inc.) have done exhaustive analysis, both from first principles and in the laboratory, and have demonstrated that an ideal case design does exist. Such a case has a powder column (behind case shoulder) near 2.1 times bullet diameter and uses an elliptical case shoulder. Patented and protected under the SMc ™ moniker, for any given case volume, these parametric design characteristics provide optimized performance with minimized barrel wear and barrel heating.
To give some idea of the potential advantage, compare the 300 Weatherby Magnum, 30/100 SMc, and 30-378 Weatherby Magnum. Usable capacity is identical for the former two; however, with best loads, the 30/100 SMc generates 10% more velocity than the 300 WM; moreover, it duplicates 30-378 WM performance, despite having 33% less usable capacity! The trouble is, no current mainstream action will handle such a fat case as the 30/100.
Sometimes, it seems as though it will be another 150 years before we are able to bring these superior designs to the shooting public but we are making headway, through its Custom Shop, Savage is now offering the 5mm/35 SMc. This is a 20-caliber varminting number that does just about anything that the 220 Swift will do and does so without heating the barrel any more than does the 223 Rem! With time, we expect to see more of these optimized chamberings offered. SMc designs, up to 6.5mm and possibly 7mm, will work through existing actions, for 30-caliber a larger action is required.









 
One more article I found interesting.

Is there magic in a case's shoulder angle relative to its neck length?
Dimensions of the 22 PPC & 6 mm PPC

By: C. Bekker

The 22 PPC cartridge was designed by Dr. Louis Palmasano and Ferris Pindell in 1974. The intention being to design an efficient benchrest cartridge. It was based on the 220 Russian case, which has a smaller head size than the 308 with a small rifle primer, a 30-degree shoulder and necked down to .224 calibre. The fact that the 22 PPC cartridge is winning benchrest matches support the theory of efficient case design, which is depicted here: -

The 6mm PPC is an outgrowth of the 22 PPC and has the same case configuration with the neck expanded to take 6 mm (.243") bullets. Body taper is minimal to ensure a firm grip in the chamber. The neck is slightly longer, .301" instead of .270", but it has the same shoulder angle of 30 degrees. The 6 mm PPC was also developed by Dr. Louis Palmisano and Ferris Pindell and is enjoying an even greater success than the 22 PPC.
This leads to the question if there is not perhaps a magic ratio between the shoulder angle and the length of the case neck. Both cartridges have the same case length of 1.515" which is considered "short". It is a known fact that shorter and fatter cases yield more velocity for the same amount of powder in relation to longer cases, but the fact that they are consistently winning competitions, seems to suggest that an ideal position or 'sweetspot' has been hit. So, let us focus on case dimensions and compare a few popular cartridges by using trigonometric calculations, and see if we can establish a meaningful trend.
There is a venturi effect, if one reduces the diameter of a pipe or nozzle and likewise when one necks down a cartridge case. The powder granules will collide and converge at some point, which can still be inside the neck or just outside depending on the shoulder angle of the case. I want to focus at this point of convergence to see what percentage of the neck is ahead of this point which apparently produce a more even pressure from then on onto the bullet. A 30-degree shoulder angle seems to create less turbulence than say a 40-degree angle, as the deflection of powder granules/gases off the neck wall is less and the collision in the centre of the neck is at a lesser angle. Thus it consumes less energy trying to get down the barrel. But what is wrong with a 20-degree angle that produces less turbulence? The only way I can rationalise this is, that the bullet swells at the base as it is pushed into the rifling of the barrel, and the 30 degree angle or thereabouts, seems to provide a more stable push from all sides to eliminate a yaw before entering, as opposed to a less sharp angle or no angle at all, where there is a greater change to gyrate as the tip of the bullet attempts to enter the rifling which also lies at an angle. I assume therefore that the pushing effect is more even, provided the convergence happens inside the length of the neck at some specific point. So, the ratio of the shoulder angle to the neck's length, will determine the point of convergence, which may be an important parameter in obtaining a sweetspot.

With trigonometric relationships, we can solve where the point of convergence is, given the angle of the shoulder of the case. I will use the 6 mm PPC as an example. The convergence point will be on the centre line of the case neck or bore, so we can divide the diameter by 2 to derive the radius or the one side of a right triangle (A) that is formed. Since the angle of attack is 30 degrees, the other angle must be 60 degrees as the sum of the inside angles of a triangle must be equal to 180 degrees. The inverse of Tan is equal to Cot and vice versa. You can either use Cot 30* or Tan 60* as they can be proven to be equal.
A = (.243/2) = 0.1215"
B = a (cot A) = (0.1215 x 1.732) = 0.2104"
(P/L) = (0.2104/0.301) x 100/1 = 69.9%

This means that convergence takes place at 69.9% or 30.1% below the mouth of the case, leaving sufficient length to stabilise the collision or venturi-effect. Short necks also cause more throat erosion than those cartridges with longer necks. Let us do a comparison now to see if there is a positive trend or at least a degree of correlation.

Cartridge
Neck
Diameter
in inches
R = Radius
D/2
in inches
Shoulder
Angle
Degrees
L = length
Of Neck
in inches
T = Tangent
R x T
P = Point of
Convergence

Percentage
P/L
222 Remington
0.224
0.1120
23
0.313
67 degrees = 2.3558
.2638
84.3%
223 Remington
0.224
0.1120
23
0.203
67 degrees = 2.3558
.2638
130.0%
22 PPC
0.224
0.1120
30
0.270
60 degrees = 1.7320
.1940
71.6%
6 mm PPC
0.243
0.1215
30
0.301
60 degrees = 1.7320
.2104
69.9%
6.5 x 55 mm
0.263
0.1315
25
0.320
65 degrees = 2.1445
.2820
88.1%
6.5-284 Norma
0.263
0.1315
35
0.270
55 degrees = 1.4281
.1878
69.6%
308 Winchester
0.308
0.1540
20
0.304
70 degrees = 2.7474
.4231
139.2%
30-06 Spr
0.308
0.1540
17* 16'
0.383
73.73 degrees = 3.2172
.4954
129.4%
300 Win Mag
0.308
0.1540
25
0.264
65 degrees = 2.1445
.3303
125.1%
In some cases the theory seems to gel, but in other cases it does not provide an explanation, for example:
1. There is general consensus that a 223 Rem cannot compete with a 222 Rem. The above table suggests a marked difference, but accuracy differences are not that big in reality. (84.3% vs 130%)
2. The 22 PPC takes a close second to the 6 mm PPC. The above statistics are indeed very similar and one tends to think that the dimensions do in fact play a strong role. (71.6% vs 69.9%)
3. None of the bigger calibres can compare with the 6 mm PPC out to 300 yards, not even the 6.5-.284 Norma and yet there convergence percentages are almost the same - 69.9% vs 69.6%. Perhaps its sharper shoulder of 35 degrees versus 30 degrees and its longer powder column come into play?
4. I expected the 308 Win to follow the theory more closely as opposed to the 30-06 Spr and 300 Win Mag. The 308 Win, with its shorter powder column and lower recoil, is generally superior over the other two longer and more powerful cartridges, contrary to what the above table suggests - a serious dichotomy! In fact, the 308 Win seems to be the worst of the bunch in terms of the theory - 139.2% which is 39.2% beyond the neck of the case and into the throat.
Here are some aspects that may vary from one rifle set-up to another:
· Capacity and shape of the case, relative to the chamber and throat dimensions, which will result in a specific operating pressure - different for each cartridge and its bullet/load combinations.
· The relative burning rate of the powder which also differ for each cartridge.
· The amount of powder used and the percentage 'case fill' - being inter-active with the above.
· The diameter, weight, and the bearing length of the bullet yielding different resistance.
· Length and interior dimensions of the barrel which refers to precision tolerances, twist rate and its consistency, number and depth of grooves, smoothness of barrel, a square crown and consistent barrel harmonics (i.e. stress-relieved or not).
· Uniformity of primer ignition and intensity relative to the loading density of the powder. If a primer is too hot for a given powder load, it will ignite the powder too fast, which will cause the pressure curve's front end to be steeper. Steep enough to slam the bullet into the rifling too hard. Probably hard enough to significantly upset (deform) the bullet's back end that it won't shoot so accurate.

So, it is not quite so simple to explain, as cartridges do have different lengths, different capacities and they all yield different pressure levels, which contributes to the efficiency of the burning, whereas the shoulder angle has to do with convergence and the neck length to absorb the collision of hundreds of particles. Furthermore, the above need to be brought in line with different throat dimensions that will affect the chamber pressure as well, as it too forms part of the overall combustion volume. Each cartridge uses its own propellant to work optimally and there is no magic formula for that. As burning rates differ, we know that some propellants work better than others in a given cartridge, and in some cases Somchem do not have the equivalent propellant of overseas manufacturers. In Rifle Accuracy Facts by Harold Vaughn, he stated the effects of bullet "cant" and verified that 'how the bullet enters the rifling' has a very dramatic and predictable effect on accuracy. He also discusses throat diameter and alignment with the bore and states that nearly every factory chamber he has studied was deficient in this regard.
So, many factors seem to be at work and it seems the jury is still out on explaining exactly the accuracy phenomenon of the 6 mm PPC, rather than solely case design and dimensions. We need a universal truth across a range of cartridges, before we can say the theory works.

30-06 Spr, 30-06 Imp & 7.82 (.308) Lazzeroni
Lazzeroni is confident though, that a shorter and wider case is the way in the right direction, as bolt flex is less in shorter actions in more powerful cartridges. Lazzeroni's cases are even fatter than the WSM's with the result that it is not easily adapted to a lot of bolt actions. The real test would be to mimic the dimensions of the 6 mm PPC in other cartridges and see if accuracy improvements will follow. For example, to redesign the 308 Winchester with a 30 degree shoulder and a 69.9 % convergence point in the case's neck, but never can the powder column be as short. Even if it cannot be mimicked, we do know that the 6 mm PPC design has hit a sweetspot. Perhaps the main reason is purely that it has a shorter and wider powder column in relation to its height, so that more powder is instantly ignited by the primer flame for a given depth, which presumably creates a more uniform burning of powder for a smoother pressure curve, which yields a smaller shot to shot variation.
Chris Bekker (
abc@telgonline.co.za)

082-772-0690

From <https://web.archive.org/web/20120505012332/http://reloadersnest.com:80/article_shoulder_angle_oct2603.asp>
 

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There must be more to it than short and fat. You can make a shorter fatter ppc sized case from br brass. But it did not take over the ppc for some reason.
I shot a .100” short 6BR formed from 7BR brass for years and it was very competitive in all SR the matches I shot. It was not better than the PPC although it was as good. As I recall I had to push the shoulder back in five or six steps then trim to length and blow out. It was a lot of work but all the original 220 Russian cases had dried up. Unless a cartridge shows a clear advantage there is no need to produce it. Recently I was reunited with a short range rifle and it is a 6 PPC not a short BR.

One day I necked a 7BR down to 17 caliber just for fun. I should have built one!

Dave.
 
Damon,

As I researched this more, I came across Fred Zigler's article (below). He notes that McPhearson's assertions of less barrel wear need more study, but his overall is that cartridge design doesn't affect velocity or accuracy.

I have not been able to find the military studies barrel erosion and cartridge design you referenced. Can you share those?


From <https://gundigest.com/gear-ammo/ammunition/ammo-case-shape-matter>
The best paper on barrel wear I am aware of was published in this book:

Unfortunately, it's on the pricey side. But there's a survey of the literature in there that goes into a lot of depth.

My semi-founded in experience opinion is that Fred Zigler is more or less correct - that capacity is bar far the most significant contributor to velocity. You could think of extreme cases (like a long, pencil shaped case) where that gets distorted, but within practical limits, I doubt it matters. You can just look through a reloading manual and you'll see that. The SMc cases are really just an example of someone trying to eke out a tiny optimization. I think it's more interesting academically than practically, though.

When it comes to accuracy, I think it does matter *a little*. Thinner cases have less bolt thrust and that is what drives vibration. There are also pragmatic reasons to want one case shape over another (ease of sizing or case life for example). But I'm very much of the opinion that matching the capacity to the caliber, bullet weight, and barrel length is the most important factor in case design.
 

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