@Webster Take a scrap case and
remove 1 grain from the groove with a file.
See if that is something you would notice.
Trim a case 0.010", weight the loss. Does that reduce the loaded volume (same OAL) or just a little brass?
Remove flash hole burrs. Can you measure the brass loss? Does loss here increase internal volume?
Groove and rim are below the case volume and would be dead weight.
Top of primer pocket to base of case is pretty much a constant.
Web thickness raises the floor and cuts down volume.
Look at a cross section and see where brass would reduce volume and where it would not.
I question the precision and correlation of most water volume measurements I've seen.
A half grain difference in case weight (in the body) would be close to 0.06 grains of water.
(Brass be much heavier than water

)
In other words, a chart showing half grain increments in case weight, should show 0.004 grams of water weight (0.004cc)
A dirty case will have micro pockets of air caught in the rough surface. That's why lab glass cleanliness is critical. A wetting agent is good for air bubbles but not micro bubbles caught in a rough dirty case.
Here are some 6mm Hagar cases with a reversed spent primer.
Weights are in grams. Meniscus variation is 0.028 grams, or 0.431 grains.
Note the straight line reflection in the last case.
(Used 6bra1k tissue wick method

)
I'll dry and redo this to see if I can repeat the measurement.
Notice the ever so slight negative meniscus.
Fairly repeatable

With the concave shape the actual weight of a full case is probably a milligram heavier than indicated or 10.6454g or so. The empty, with spent primer is 8.3442 grams. Water weight of a full case would be 35.512grains.
EDIT:
Did a slightly heavier case. Rounding to 3 decimal places (nearest 1mg)
First case was 8.344g empty, 10.645g full=2.301 cc (35.509 grains of water)
Next case was 8.584g empty, 10.860g full=2.276cc (35.1245 grains of water)
8.584-8.344=0.24 grams of brass difference, 2.301-2.276=0.025 grams of water difference.
Brass to water 9.6 to 1.
Sounds reasonable to me
Dead weight vs volume reducing weight. Where is the most likely place to find a few extra grains of brass?
Rim and groove?
