I had a carbon ring build up in my last Dasher barrel that I shot for PRS and practice. Cleaned it every couple hundred rounds with Hoppe's #9 and cleaned out the copper with Wipeout every 500-600 rounds, nothing very aggressive. At 1800 rounds, on a "clean" barrel, I was getting wild velocity changes with SD's jumping from single digits up to 30-40 fps swings. When you chambered a round you could see marks all the way around the bullet on a load that should have been jumping 0.020" to the lands.
I cleaned the carbon ring out using CLR (on the advice of another shooter). Wet patch down the barrel, couple quick brushes with a nylon brush, then place a second wet patch in the throat for 5-10 minutes. Pulled the wet patch out, spun a nylon brush in the throat area a couple dozen times (just twisting the rod by hand), then patched and cleaned out the CLR afterward with dry patches then a couple wet Hoppe's patches. Repeated that cycle twice.
Completely solved the problem, rounds chambered easily with no marks, SD went back to single digits where it should be, gun was shooting well and went and shot another match with it.
As noted earlier, CLR is pretty harsh stuff (acidic) so I'm not sure I'd use it too often or leave it in the barrel for an extended period of time.
I cleaned the carbon ring out using CLR (on the advice of another shooter). Wet patch down the barrel, couple quick brushes with a nylon brush, then place a second wet patch in the throat for 5-10 minutes. Pulled the wet patch out, spun a nylon brush in the throat area a couple dozen times (just twisting the rod by hand), then patched and cleaned out the CLR afterward with dry patches then a couple wet Hoppe's patches. Repeated that cycle twice.
Completely solved the problem, rounds chambered easily with no marks, SD went back to single digits where it should be, gun was shooting well and went and shot another match with it.
As noted earlier, CLR is pretty harsh stuff (acidic) so I'm not sure I'd use it too often or leave it in the barrel for an extended period of time.