Other than the explosion at the end, I had a bottle of 4166 go bad in a similar fashion.
I tried several different loads with 4166 in my 308, and could never find a load that worked. Eventually, I gave up and loaded some plinking rounds to practice with. When I loaded the rounds, the powder appeared normal.
When I shot them about 2 months later, I got several very scary hangfires (about a 1-2 sec delay). I pulled the unfired bullets and found thick green corrosion inside all the cases. The remaining powder in the can had also started to degrade. It was letting off some really acrid fumes, and it almost looked like smoke coming out when I opened the bottle. The white foam seal in the lid crumbled into dust, and the plastic bottle was deformed and bubbly. It didn’t feel warm or anything, though.