New brass, Norma as they're the only ones that make it, holds 83+/- gr. H20 My fired and FL sized cases hold 84 +/- H20. I mentioned, FL sized, because they'll hold more fired and unsized but to me that number is pointless.
RL33 is considerably bulkier, more similar to powders like Retumbo that take up a lot of space, than is RL26 so I'm surprised you can even get enough in the case, without a good amount of crunching, to get that kind of velocity, especially, since you mentioned your 7 Rem mag has a match reamer with a standard throat which means not a lot of freebore. But, the fact that you don't have a lot of freebore and you're shooting really long bullets very possibly means you're right at touching the lands or maybe even in to them which will spike up pressure leading to higher velocities.
Generally, powders like RL26, in cases of this size, produces the best velocities. The slower and bulkier powders like RL33, Retumbo, and N570, again in these size cases, are usually down on velocity because you run out of room in the case before you can get enough in there. The much bigger and overbore cases like the 7 RUM or 28 Nosler, where you have a lot more case capacity, is where those slower powders shine.