I'm a guppy here, but it seems to me that case volume may not have noticeable effects on performance. ......... snip............
You may be correct, but that might depend on the definition of "noticeable", to paraphrase one ex-President.
Here is some data I collected. Some time ago I measured the water capacity of several samples of my .223 Lapua brass. The H2O water volume varied by a little less than 1% and this volume varies with the case weight. But does that matter? The short answer is that I'm not sure, but I think it might.
I shoot F-class and I do enough testing to know that actually proving a performance difference between light and heavy brass caused by variations in volume is a fools errand.
I'm convinced that changes in performance caused by annealing every time vs every 5th or 10th time are bound to be very small. But that doesn't mean annealing isn't worth doing. I anneal every time. I also weight sort bullets, neck turn my cases, uniform my primer pockets, deburr (or at least inspect) flash holes, chamfer case necks, and all the other steps most competitors perform. I stop short of weight sorting primers.
Anyway, since most of us test by shooting bullets over some significant range through an unknown atmosphere out of a gun with an unknown barrel temperature which is held by a human, etc. etc. etc. it is no surprise that any change in performance caused by uniforming a primer pocket, for example, as opposed to leaving it alone will be lost in the noise associated with the way we collect data.
Nevertheless, I'm convinced that all these tiny performance improvements, even if they're only theoretical, probably add up to improve performance at the target. Just because I can't prove something doesn't mean it isn't real.
Having said all that, I took a look at my latest Quickload .223 recipe this morning and changed the case volume by 1%. The calculations showed a change in MV from 2948 fps to 2936 fps, not very much. I took those two figures and plugged them into my ballistics app. At 600 yards, Quickload claims that the slow bullet will impact one inch lower. Again that's not much, but ask any F-class competitor if he would like to reduce his vertical by one inch and you will get a unanimous YES. Remember, the X ring is only 3" in diameter.
So I weight sort my brass into three lots, light, medium, and heavy. Since F-class matches usually consist of three strings of 20 rounds, I segregate the brass so that even though every round may not be the same, all 20 rounds in each string are as uniform as possible, or to tell the truth they're as uniform as I think reasonable. You gotta' draw the line somewhere.
I hope that by sorting my brass I can reduce the vertical dispersion at 600 yards caused by case volume from one inch to something less, maybe 1/2 inch or even 1/3 inch. Will that help? I believe it might because 1/2" is roughly 10% of my total vertical dispersion. A 10% improvement in any area is probably worth making.
I won the match last weekend tied in points with the 2nd place guy because I shot one more X than he did. And I've lost matches by that amount too.
Of course, your mileage may vary, but I'm going to continue to weight sort my brass for F-class matches.