In order to truly answer your question, you would have to know the exact frequencies of your barrel, as well as understand in detail how the different modes of vibration affect muzzle displacement. I am one of the practitioners referenced by CharlieNC that believe that optimal barrel times are real, but that they are probably not explained by a longitudinal shockwave traversing the barrel. Personally, I believe that the concept of optimal barrel time "nodes" probably fits somehow with at least some of the higher order barrel harmonics, although that has not been proven scientifically. Nonetheless, I have had very good results loading to specific barrel time node over the years. In fact, the results with multiple different rifles and calibers have been far too good to believe it is merely chance.
For a given length barrel, if you know the frequency at which it vibrates, it would be tempting to think you could simply subtract one OBT from an adjacent node in the Chris Long's OBT Node Table and determine whether the resulting difference was anywhere close to 1/2 the frequency, or the time it would take to move from the top to the bottom of its arc of travel. Unfortunately, measuring barrel frequency takes specialized equipment not owned by most shooters and the system is far more complex than that.
For example, the frequency of 1st order (Mode 1) harmonic motion at the muzzle analogous to the end of a model cantilever beam is relatively slow, perhaps on the order of 50 to 75 Hz, depending on the barrel and load velocity. That means the time it it would takes the muzzle to go from the top of its arc to the bottom would be around 13 to 20 ms (i.e. 1/frequency). Optimal barrel times would therefore need to be much longer than they actually are reported in the Table, more on the order of 10 to 20 ms, for Mode 1 to be the target. So the explanation of bullets exiting at the top of the barrel arc for one OBT node versus the bottom of the arc for the next OBT node is too simplistic and does not fit with actual measured data. In fact, the frequency of Mode 3 (around 1000 Hz) represents a more likely way in which optimized barrel times could mesh with barrel harmonics.
Another thing to remember is that OBT Nodes as listed in Chris Long's Table are not the only "accuracy" nodes. In fact, they are spaced pretty far apart based strictly on the values in the Table. In other words, velocity from a given barrel length must be increased/decreased substantially in order to hit the next adjacent OBT Node in the Table. If you use a ladder or some other form of load development testing that clearly reveal accuracy nodes, you will find that there are clearly other nodes in-between the values of the OBT Table. In terms of barrel occupancy time, these other nodes are clearly not as far from a given OBT Node as the OBT Node itself is from the next OBT Node.
So what does all that actually mean? To be honest, I have spent some time in the past going partway down that rabbit hole, but ultimately refused to go any further. There are many resources available to you if you wish to pursue some unifying theory between barrel harmonics and the concept of OBT. Personally, I find it much easier to load up a test series, go out and shoot them, and then let the target tell me where the rifle wants to tune in. I'm basically describing the difference between empirical and theoretical information. There are certain things we can readily do and obtain useful information from, without necessarily understanding the mechanism of how they work in exquisite detail. So you can easily develop a load that shoots extremely well without using any reference to barrel occupancy time, then go back later using QuickLoad and determine for yourself how well the barrel occupancy time of that load matches some value in the OBT Table. If you do that exercise a few times, it ought to be enough to convince one way or the other whether OBT Theory works in your hands. Personally, I very much like to understand WHY things work the way they do, especially with regard to ballistics, but I often keep coming back to a very simple idea that usually gets me where I need to be:
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