I'm a little late to this parade, but I'll chime in with my experience so far shooting the 90 VLDs. I have a GAP rifle with the Templar2 action, single feed, coned bolt, and Bartlein 5R (.218"/.224") 30" barrel. I bought the RemISSF reamer from Dave Kiff at PTG that has .169" freebore. My load is 24.0 gr (current lot) H4895 in Lapua brass with the bullets seated ~.015" off the lands (2.636" COAL). I am getting right at 2850 fps with this load, which gives a barrel time in Quickload of 1.371 ms, just a tick slower than the OBT node (1.2684 ms for a 30" barrel).
I've given a lot of thought to how the performance of the 90 VLDs might be improved, even just a little bit, from what I'm currently running. Laurie Holland is a real expert in this area, having worked on the same idea for some time. The main problem in trying to increase velocity is that you're really running up close to max pressure in terms of brass life, as well as the magnitude of increase in velocity that would be necessary to reach the next OBT node. I would love to be able to shoot the 90s at 2900 to 2950 fps. You're talking very close to 200 gr Hybrid performance in a .308 at that velocity, with almost no recoil to speak of. Unfortunately for me, I can easily push them that fast, but brass life is remarkably poor and it's not on an accuracy node. Without precision, velocity means little.
You can play around with a variety of different parameters in Quickload to try and predict some combination of barrel length, powder, freebore, etc., that will give you higher velocity than the 2850 fps I'm currently getting. Unfortunately, if it doesn't coincide with an accuracy node it's not going to buy much. I can easily get the 90s faster than 2900 fps with my current setup, but brass life is nonexistent and accuracy/precision is poor. In my hands, reaching the next OBT node velocity-wise is pretty much impossible...it's way, way up there. The best I have been able to accomplish at this point by modeling different setups in Quickload is to determine that by going with a longer throat (i.e. > .200" freebore), I can probably extend brass life significantly while remaining at the ~2850 fps node. However, velocity at the OBT node really doesn't go up by much by increasing freebore or barrel length, so there wouldn't be more than a marginal improvement in ballistics. So you can likely improve the pressure issues, but not by nearly enough to reach the next OBT node. For now I will continue to play around with various combinations to see whether it might be possible to push the 90s to the next level, but I'm afraid I'm probably already at the max ballistic performance I'm going get with my setup. The good news is that this rifle shoots extremely well out to 1000 yds as it is. I've shot it in enough competitions now that I'm comfortable saying I'm not giving up anything to my .308 185 Juggernaut load by shooting the .223, even in tough wind conditions. When you add in the almost complete lack of recoil, this setup is a real pleasure to shoot.