As Terry suggested, it is possible to seat the 80.5s in a rifle chambered for the 90s (at least in a .223 Rem case) as long as the freebore isn't excessive. For example, in a .223 Rem chambered with PTG's 223 Rem ISSF reamer that cuts 0.169" freebore, there is sufficient shank left in the neck when seating the 80.5s. I have loaded some dummy rounds with the 80.5s at ~0.020" off the lands and they are seated well out in the neck, but would work just fine.
However, it all depends on the specific chamber and how far out the neck the 90s are seated. IMO - the 0.169" freebore cut by the original PTG 223 Rem ISSF reamer is not sufficient for the 90s if they are seated ~.020" off the lands (or longer), which is where mine usually end up. In that scenario (i.e. 90s seated at ~.020" off the lands), a 0.169" freebore chamber will put the boattail/bearing surface junction just barely above the neck/shoulder junction. For that reason, I had a new reamer designed for the 90s with substantially longer freebore (0.220"). Although I have not checked it directly with dummy rounds, I suspect in a chamber cut with that reamer, seating the 80.5s might be problematic. I'd imagine there might only be about 0.050" worth of shank left in the neck with the 80.5s in that rifle. So as long as you don't "optimize" the freebore for the 90s all the way to the long end, it should work just fine with the 80.5s.
In order to clear the donut, the boattail/bearing surface junction of a seated 90 VLD should be somewhere well above the neck/shoulder, but probably doesn't need to be as far as halfway out the neck. So it might be close, again, depending on exactly how much freebore the chamber has. If you have both bullets in hand, setting up some dummy rounds might give you a better picture of how far out in the neck the 80.5s would be seated. Another option would be to select a different ~80 gr bullet that has a noticeably longer base-to-ogive dimension than the 80.5 Fullbore, such as Berger's 82 BTHP, or Hornady's 80 gr ELDM. I haven't personally tried either one, but have heard good things about both from people that have.