Dusty,
If you asked 5 guys what they use, you may get 5 different answers. Many use Tap Magic, Viper's Venom, or like just plain lard.
I've used several brands and don't have a favorite. Since I have a large supply of Viper's Venom, I've been using it.
As far as finishing a chamber there has much written about it. If you search a little you will come up with enough info to be confused.
If you think about it, all you are trying to do is, make the chamber smooth, easy to load a round into without scraping the wax off and ensuring the leade (transition) is smooth and even all the way around with no fraze or burs. Really doesn't matter what you use as long as you accomplish this. As I mentioned shooting enough rounds will normally get this done but it will take time and ammo.
Many chambers have been ruined by not seasoning them properly. If you don't remove the carbon build up from a new chamber often the leade may wear unequally. Once this happens the barrel has lost some of its potential.
TKH (4628)