Cole, I'll offer a few thoughts, but my first one is that the .223 has been, in my experience, one of the toughest cartridges to get a low ES/SD out of. I could speculate why, but I don't have hard facts on that, it just seems to be that way. Now, on to some hopefully helpful ideas:
1. Personally, I find SD to be a more relevant measure of my loads. SD is a measure of the load's overall consistency whereas ES is a measure of the two worst shots. It's almost the same concept as group shooting,ES) vesus score shooting,SD). Suppose you fire a 20 shot string over the chrono and 19 of those shots have a velocity of 2850 and the 20th is 2900. You were doing a pretty darn good job of loading. The average vel. is 2852.5, but the ES is 50 and a lot of people would look at that and say it's a bad load. However, the SD was 11.2 and is indicative of a good load.
2. Now, suppose that your shots were half at 2875 and half at 2825. The average vel. is 2850 and the ES is 50, about the same as before, but the SD is now 25.6, more than double. Why? Because the load is much more irregular. SD is essentially a measure of how far from average you can expect a given shot to be,that's a fairly simplified description, but useful). SD considers all shots fired, not just the extremes.
3. A shot that is more than 3X SD from the average is a fluke which can and should be discounted when making calculations. They will just happen, even with perfect loads, that's part of the randomness that exists in any population. I would pick the 11.2 SD load every time in the above examples.
4. That's a nice discussion of statistics, but it doesn't get you to a better load, does it? Some loads are just not going to ES/SD well even when assembled perfectly. Powder type, burn rate and amount are big factors here - as are primers. I think you're using the best possible primer for a small rifle case, so I'd focus on the powder type and charge. Your combination isn't one I have shot, but RL15 might be a better choice as it tends to give good results in .223 with 69 and 80 gr. bullets. The 77's are kind of different because of their long bearing surface, though, so it's not a sure thing - but probably a good one to try. I suspect that the biggest part of your quest will be in powders.
5. One last tip from a lot of chronographing is that how consistently you hold the rifle affects the MV of the shot and thus all the statistical results. I can alter MV in a predictable fashion by holding loose or tight. Make sure that you are consistent in the grip and shoulder pressure when firing over a chrono.
6. Handy SD calculator: http://www.easycalculation.com/statistics/standard-deviation.php