I did not run the test as exactly you stated, but it's looking like I may have to go back and start over.Oh my, that's a word salad, and was a disincentive for watching the video.
By "optimizing" velocity, I read maximizing velocity.
As I have learned from decades of reloading and shooting, chasing speed is a fool's errand. Optimizing, to me, is finding that sweet spot marrying the most consistent MV and most accurate on target.
My understanding of what I read is that the ultimate intent of your experiment sought to determine if you could get the same velocity out of a shorter barrel by using a faster powder.
As @Doom wrote, burn rate is affected by pressure, and thankfully we (generally) don't have to worry about rifle powders detonating (runaway burn rate) once a certain pressure is reached.
Peak chamber pressures is the ultimate determinant of MV, and the completion of the burn as the bullet travels down the barrel will affect the rate of acceleration. The trade-off, as I believe @dellet mentioned, is higher pressure and report at the muzzle.
The higher the pressure behind the bullet as it exits the muzzle tests the consistency of your rifling and crown. There is a point where this has marked affects on your accuracy.
Coming back to your experiment, I hope you optimized powder charges for the same bullet in the same barrel, then repeated the optimization for the different powders using the same bullet in a shorter barrel.
It appeared to me that this would be a slam dunk and I thought the faster powder was going to be faster velocity in the short barrel by a long shot.
Velocity is a fools errand for hunting accuracy, no doubt, but trying to get bullets to do what bullets are designed to do out of 11.5 inch guns is quite difficult at times and every 50 fps seems to matter.
And the loads which I developed for my varmint rifle shoot the worst out of that carbine at about 2 MOA, but I've never shot really anything out of that gun, I think due to its length and heavy barrel contour that don't shoot pretty decent, at least decent enough for the job.
The hunt for the maximum velocity in the 11.5 was to see whether it was intuitive to just make a fast burner powder load for the short barrel and get the best possible velocity, which doesn't exactly seem true. And the reason for the velocity hunt is that I've got 50 grain V-max loads for the 11.5 inch guns and 75 grain loads for the 18 inch guns, but if I could find a load that shoots 2500 feet per second out of the 11.5 with heavy bullets, I'd rather have that, so the fools errand is what it is, but I'm driven by a preference.
Lots of testing to do, but I'm going to keep plugging at it and you old boys do help as I go along, even when you're adversarial about the way I speak.