Expand the .220 Russian (lube case necks and mandrel) to 6mm, and neck turn with enough cut depth on the shoulder so that there is feel when you close the bolt, but not much effort is required. This is a trial and error thing. Clean the cases, taking care that no lube remains, inside or out. Size the case necks with at least .003 neck tension. Prime the cases with Federal primers (They have softer cups.) Fill cases with as much 133 ,322, or benchmark as you can fit behind the bullet without compressing unduly, and seat bullets long enough that they are well marked by the rifling. Fire these in any barrel that you like. They will not hurt a thing. As usual, don't get in too much of a hurry, because that may elevate barrel temp. to an undesirable level. If it is a new barrel, you can combine fire forming cases and breaking in the barrel. I don't spend too much time on barrel break in, no more than five or six one shot and clean cycles, and then a few three shot groups. Twenty cases is plenty to start with. If you are one of those I plan on getting set up to load at the range later guys, get over it. Get set up now. It is really no big deal at all. Ask if you need help. After fire forming, trim to 1.490, lightly debur, and very carefully chamfer. Don't bump back case shoulders on the next sizing because the shoulder to head dimension will not be at its maximum. Wait till you see that measurement stabilize, and don't shoot top node loads for the first 2-3 firings. You can go warm, just not the hottest. I like to to a pressure series with a single case that I reload after each shot, and keep as a reference for maximum case "headspace". That way my main set of cases should be more uniform. I try to keep them as much alike as I can, and usually have a practice set of 5-6 for trying out ideas. This is a very common method that has been in use, for decades by hundreds, if not thousands of shooters. There are other ways, but this is probably the safest for the one barrel guy. You may be surprised as to how well your fire forming loads group. This is not always the case, but it has happened more than once.