I can say with certainty that my chamber reamer is specd to 0.502 at the 0.200 line and measured somewhere around 0.5025. My brass was coming out of my chamber after multiple firings with the largest diameter being 0.503 (or 0.5035 can't remember) just forward of the 0.200 line. Sizing die wouldn't size it down any further than 0.5025 even though the 0.200 line on my resize reamer was 0.4985.
This is with Peterson brass that measures 0.499 at base.
There's a lot going on at once here but I'll explain a few things and hope it will be of help to someone, either now or later.
First off, the virgin brass dimension means nothing in this context so lets move on from that. It's only virgin once and has no bearing on this discussion at all. Spec'ing a reamer based on virgin brass is asking for problems rather than curing anything.
Second, a half thou is not much at all and I would not call it a bad chamber based only on that. This based on your specs of .5025 for the reamer and .503 or .5035 for the multiple times fired brass. Granted, if it's .5035, that's pushing it a bit more than I'd like to see.
Now, why do we size brass? Every time we pull the trigger and the round goes off, the resultant pressure literally swells both the case AND the chamber a bit. Someone else can probably calculate how much better than me but I certainly wouldn't be surprised by a couple of tenths or maybe more. So, the brass develops a memory and wants to go back to it's largest expanded state and loses it's ability to spring back(constrict) as it gets harder and bigger with each firing. That's why it gets tight in a chamber after a few firings, especially hot ones, and why we have to size it back down. FWIW, some pressure testing equipment use strain gauges attached to the bbl that measure this expansion of the bbl and convert it to current and can be graphed, just to support that the bbl does in fact expand under pressure..believe it or not.
Now, to your fired vs sized case dimensions vs your resize reamer dimensions(.4985). You stated that your die sizes your multiple time fired brass to .5025 and unsized brass measures .5025-.503. That's just about where it should be and what you should expect. A resize reamer is very typically .003-.004 smaller than the chamber reamer because the brass springs back considerably after sizing. So, it's entirely normal and necessary to size the brass down that .003-.004 to yield .0005-.001 of actual sizing..or what the sized brass that you load into the gun should measure. Again, this is normal and how it's done, and I've just tried to explain why.
Bottom line, based on your numbers, there's just really nothing hugely wrong with your chamber or die. Not saying it's perfect but it's certainly not bad and should have no negative effect on the target and I see nothing in the numbers that are off enough to be of any concern, really in any regard at all. If it shoots well, go shoot and enjoy it and I suggest you worry less about the chamber/die dimensions unless you have problems from it. I've seen lots of steel that made this much difference or more in the finished chamber dimensions from the same setup and reamer. Some will cut a tad tighter than others. Again, believe it or not. We throw around tenths like it's some big amount but it's really not and we are chasing a bit of a moving target when we talk about different steels and different brass, different pressures, how many firings and all the variables at play. There has to be some margin or it creates problems rather than helping.
Again, I hope this is of help to you or someone down the road. You may know all of this but maybe everyone didn't and they will benefit from reading this and seeing that there's just a bit more to it than meets the eye is all. Good luck and good shooting !--Mike