If two cartridges, one a .224" (220 Swift for example) and the other a .458" (458 Win Mag) are loaded to equal pressures, 60,000 psi the 22 will send a bullet from case to muzzle in about .001 second while the 45 will have about double the time in the bore. Since the 45 bore would be exposed to the same pressure but for twice as long, why does the 22 barrel burn out twice as fast as the 45?