Perhaps what's needed is a combination of materials ,for the ultimate barrel . A SS barrel with an infused compressive bore of one of the below materials . Making the bore impervious to corrosion and wear . Just a thought . I'm still working on the BAM application ,as it's proving to be a superior applicable anti wearing material .
According to PhysOrg.com article from 2009, a material called wurtzite boron nitride has a greater indentation strength than diamond. The scientists who made this discovery have also calculated that another material, lonsdaleite, is even stronger than wurtzite boron nitride and 58 percent stronger than a diamond. This discovery marked the first case where a material exceeded a diamond in strength under the same loading conditions.
The extreme strength of the two materials is due to their reaction to compression. Most materials undergo a structural transformation under pressure that makes them stronger. Lonsdaleite and wurtzite boron nitride have subtle differences in the directional arrangements of their structural bonds, making them stronger than diamonds under pressure.
Needless to say, as I am sure you are well aware... that material parameters and Mother Nature are cruel...
I was often asked by inexperienced leaders why I couldn't solve a problem with something they read about and got too excited.
They tended to get very excited by a parameter or discovery that hit some new extreme and insisted that it be applied to their cause. As an expert I had to let them down softly as they could make my life difficult if they took offense. Before we get too excited here, as someone who had to work on gun barrel materials and weapons systems problems, I will caution folks not to stare at one property too hard while ignoring all the others and wonder why it doesn't revolutionize the industry.
Once in a great while, we do in fact get a performance improvement from the discovery of a new extreme.
On the other hand, things like DLC, H-DLC, and a variety of diamond like coatings have not been the silver bullet that those managers demanded. Sure, many problems have been solved with hard coatings, but even those took lots of hard work and time to balance. Management expected results instantly, but my advice was to expect it to take years on average if the topic was to apply a new hard coating on an existing problem, and I might not end up using the one they read about in the end.
There is often a balance that requires the concepts of harness and ductility to be played against one another in a trade-off. For example, if we get things too hard and focus on compression loads, we often get brittle failures due to tension tension loads.
The keys to the problem are to take a look at all the loads and all the environmental issues that drive the problem. In our example of a gun barrel, we get to consider pressure, tribology and heat, as well as economics and producibility.
High Pressure in a gun barrel means the material sees high tension, not just surface compression and wear. Crack propagation and tensile failures in the substrate (base metal under the coating) are not the friend of very hard materials. Some diamond like surfaces are very abrasive instead of being low friction depending on the environment. Most are produced by methods that don't lend themselves to producing any shape or surface at will. ID coatings are not the same difficulty as OD coatings as a result.
Gas processes and things like nitriding have been used to improve the performance life of many complex shapes and parts, but I will tell you the processing changes often take many trade-offs and trials before we are happy. Ever wonder why we don't just salt-bath nitride every gun barrel? On paper, the process sounds like an instant success, but in practice it takes development and time to learn it isn't a silver bullet.
Sure, diamonds are hard, but have you ever seen how easy it is to cleave one? Mother nature plays her cruel trick on that crystal structure when you are not looking. To get past Mohr's Circle, you have to work pretty hard. If we push too hard or get distracted by compression harness alone, we get smacked by tensile and shear. Even then, when we get all three, there are still dimensions like tribology, corrosion, toxicity, fabrication, and economics to keep us humble.
I'm retired now, and wish the material researchers luck. The current administration's views on materials R&D are pathetic, so I will watch from the sidelines and cheer.