There is quite a bit of good info here on slugging and what to look for. I would like to add a few things myself with the preface that 95% of my barrel work is typically for rimfires where usually the barrel lives and dies by how it slugs (lead bullets) and where the chamber and crown is located on the blank. It is pretty well known that the rimfire blanks of quality are taper lapped from the manufacturer because of this but a person still cannot just blindly pick a spot to cut and crown. I have and will likely always continue to do my CF barrels the same as I outline below.
I think the idea posted earlier of "mapping the bore" best applies to what I am doing when I am slugging either a new blank or a fitted barrel. On a new blank, I will typically use about 15 slugs to get a complete picture, with measurements, of what the bore is doing. I will push 2 slugs through the bore, breech end to crown end to get an idea of the bore to start, then I will push individual slugs in from the breech end, incrementally in steps, and then push them back out of the breech end to preserve the diameter at that spot for measurement. My increments are 1", 2", 3", 6", 9", 12", 16", 20" from breech, then 3", 2", 1" from the crown end. I will mark all of these increments on my slugging rods and push the slug from the breech end up to the desired mark, then push the slug backwards out the breech again. My opinion, pushing the slug backwards can almost tell you more about the bore than pushing it forward based on how easily and quickly it will release the bullet, if at all. While I am pushing all these slugs, I am marking the spots that I feel something funny or odd to see if a pattern comes up. I have done many barrels in the past that on the reversal of the slug back out of the breech end, I detected some sort of odd spot in the bore, usually roughness, that I never felt pushing the slug forward. Then the final two slugs are used to feel for any of the anomalies I may have felt during the process and either confirm or deny them. After all of this, I will mark the OD of the blank at my increments and measure each slug and record the measurement at each spot of the bore. When you finish up, it gives an easy visual up and down the blank how it tapers, if it does, and what places may be best to establish the throat/leade of the chamber and most importantly here the crown.
I am not suggesting that my practices are the best for everyone, it is a ton of sorta aggravating work, but I will not fit a barrel without doing it. I use pulled bullets from cheap lead rimfire rounds. They have worked fine for me with .22CF barrels as well, occasionally having to bump them a tick bigger to fit the bore better. Cheap lead bullets that are not coated or full of lube will work fine for the larger calibers as well once they get started in the bore. One thing that I do differently is that I do not lube the bore or slug. This post has gotten entirely to long to explain it further but I did want to note it.