The 6.5-twist barrels will obviously shoot with 90 VLDs. However, there are a couple considerations to going with a twist rate that fast. The first is, you don't need it at most shooting venues. A 7.0 twist will net you almost the full intrinsic BC; according to Berger's Twist rate calculator, a 7.0-twist barrel pushing the 90s at 2830 fps at 500 ft elevation and 65 degrees is only giving up about 2%. As the elevation/temperature increase, that only gets better.
The second issue with a faster than 7.0-twist barrel concerns jacket failures. These seem to occur more frequently with barrel twists faster than 7.0. They also seem to be exacerbated by high temperatures. In a different thread, it has been suggested that frictional heat at the jacket/rifling land contact points causes the surface of the lead core to melt. When combined with a small crease or tear in the jacket, molten or vaporized lead will exit through the hole, creating "comet tails" around the bullet holes on the target face. This event seems to be associated with, or at least, preliminary to, jacket failure. There are ways you can try to minimize the possibility of jacket failure, such as running a couple wet patches of Kroil followed by a few dry patches after each course of fire to minimize carbon fouling, moly-coating your bullets, using a powder/load that tunes in at slightly lower velocity than H4895 in a 30" barrel, using a more "jacket-friendly" land/groove shape such as 5R rifling, etc. Nonetheless, losing a jacket in most F-Class competitions will put you totally out of the running, so it's not something you want to have happen, even once. Not everyone running a faster than 7.0-twist barrel has experienced this problem, so there are clearly other contributing factors we don't as yet fully understand.
Shiyfire - I'm not trying to scare you off about the 6.5-twist barrel here, just bringing up the considerations for other readers that might be thinking of running a twist rate of less than 7.0 with the 90 VLDs. With your 22" barrel length, I doubt you will be approaching the velocities with 90 VLDs (2800+ fps) achieved from 30" barrels where this issue seems to be more of a problem. With the appropriate long freebore (>/= 0.169") and COAL (>/= ~2.630"), Quickload results suggest that with a 22" barrel, you might find accuracy nodes somewhere in the neighborhood of ~2575 fps with H4895 and ~2550 fps with Varget. Those values may seem a little slow as compared to 30" barrel velocities, but are actually pretty impressive for a 22" pipe with such a heavy bullet, given that most commercial 77 gr SMK loads only have predicted velocities of 2600-2650 fps from a 24" test barrel. I'm guessing the faster twist rate won't be an issue with a 22" barrel. Have fun with it!