Determining case volume with water is not that difficult an exercise, but it takes a fair amount of time if you plan to do it for all the cases you intend to load and fire:
http://forum.accurateshooter.com/threads/case-volume-determination-pic-heavy.3896148/
There are caveats to using case weight alone to sort brass, as has been noted above. Case length, width/depth of the extractor groove, and base-to-shoulder dimensions are all factors that will affect case volume without altering case weight. I've sorted many, many cases by weight where I also determined case water volume and plotted the results. If case weight was
always perfectly proportional to case volume, each of the case weight versus case volume values would lie exactly on a straight line with a negative slope, which is not what is normally observed. You will usually find some outliers where cases sorted by weight alone exhibit a volume estimate value that is well
off the curve of case weight versus case volume, as determined using water weight. Nonetheless, sorting cases by weight alone will almost always give you much more consistent internal volume in your sorting groups than not sorting at all.
Only you can decide whether your shooting needs and available time require/allow you to do the extra diligence necessary to sort cases by water volume.
FWIW - I shoot in F-TR and will likely never see the effect on the target of minor variance in case volume that arises from sorting cases by weight; it is simply not the limiting factor in terms of precision for what I do. So I typically determine water volume for 20 cases or so from each brass prep to obtain an average case volume value for use with QuickLoad, then sort cases by weight when loading for a match.