Shooting a king-kong magnum with 90gr plus of slow powder? Gonna see some residue on the necks.
Got the action cerakoted? Was the boltface trued or coated?
A caliper won't measure neck thickness, as the other guy alluded to. Ball micrometer and should read in ten-thousandths, or an ID reading tube mic of same calibration.
But...Inquiring minds and all that... How many rounds on your barrel? What did the brass measure oal to shoulder before and after firing?
Don't sweat the small stuff, guy. The KK magnums are barrel eaters. If you got 250 rds fired through yours already, probably time to order-up again. Maybe let Pac-Nor, Hart, or Shilen do a pre-fit job. Pull your barrel and give them bolt nose and boltface measurements to the receiver shoulder, they will dial you in and give you the chamber you want.
Really want a min oal chamber even with a KKM. Had a few KKMs 7-8yrs ago. Decided did not need the Barrel Scorching with every touch of the trigger. Call Sierra and ask their tech boys/girls how long your .300rummy ought to last? .30-378, .338rum, .300rum all gone and glad of it... Each to their own.
Might try shooting your same loads in the now chamber-formed brass and see if your concerns are alleviated. Better still some older brass you know had no issues.
If you shoot only handloads, check the oal of virgin and 1x fired brass on a Wilson Case Gauge, or RCBS Precision Mike; you might be very surprised at the variance.
If you are trying to shoot mild loads w/anything other than cast boolits in your KKM, there is some danger there. Too mild and you risk detonation. If you aren't filling-out your virgin brass to full chamber dimension, you probably don't want to go any lower. With fully formed brass, it wouldn't matter (within reason). Anything of full-length H&H Mag case dimension is too big for mild loading with typical magnum powders.
One other thought, Using Federal 215 magnum primers? The Primer specifically developed for KKM uses? Might want to, so to be sure of complete powder ignition. Maybe that is part of your smoked neck issues?