Two factors combine to give a bullet's BC value - form factor and sectional density (SD). SD is fixed by the calibre and bullet weight, so a 224 80 always has an SD value of 0.228 and a 90 is always 0.256.
The form factor is the more interesting value in many respects as it's a numeric value put on the bullet shape, ie its aerodynamic efficiency. The factor is always a comparison to the 'reference projectile' which in our case is best met by the G7 model and as it's drag based, the lower the value the better. The 'reference projectile' is always given a value of 1.000, so if a bullet has that value it's equally efficient as the G7 model, if less it's more efficient (and gives a higher BC when combined with the SD), if higher it's poorer and produces a lower BC value.
The benefit of form factor values is that you can compare different calibre / different weight bullets and it gives an idea as to how clever the designer has been and also an indication as to whether there is more to be wrung out of the calibre with better designs - albeit you can't get equally good form factors across all calibres as the larger calibres might need way too long and heavy designs to match the best 6.5s for instance.
The very best (lowest) FF values have been found in the 6.5s in modern designs. The 140gn Berger Hybrid at 0.905 a shade less than 10% more efficient than the already effective G7 reference is a good example, but there are a very few that slip down into the high 0.8s, such values found in no other calibre for traditional jacketed / lead core designs. The best of the 7s are slightly higher in the 0.920s and that's where the new heavy (>200gn) .30 Hybrids are.
So, we can compare the 0.224 80s and 90s against them. Remember this isn't BC as you have to add in the bullet weight / calibre bit too and equivalent different calibre bullets can be driven at diferent MVs within the same maximum pressure ceilings.
So (source Bryan Litz) we get form factors for the heavier 224s of:
80gn Sierra MK ............ 1.048
80gn Berger VLD .......... 1.001
80.5gn Berger BT ......... 0.979
80gn AMAX .................. 0.987
90gn Sierra MK ............ 0.999
90gn Berger LRBT ........ 0.979
90gn Berger VLD .......... 0.911
What this tells us is that the existing and been around for a few years 90gn VLD is an outstanding design both in relation to newer designs in other calibres (marginally lower than the new 105gn 6mm Hybrid) and in relation to its fellow 22s.
So you wonder why Berger isn't pushing / developing the model. In past email correspondence with Bryan Litz, he has been cautious, almost cool, on the subject of new ultra-heavy (ie 90gn) 224s. I suspect that's because the bullet is at the limits of overall length in relation to calibre and is likely pushing the boundaries of good bullet design. It works very well for some, not at all for others in optimally specified L-R 223s for FTR and similar. Even where it works, the occasional unexplained 1,000 yard elevation flier appears and it's not just that every factor of the rest of the 223 package has to be 100% right and consistent that explains this.
So, from Bryan's comments elsewhere on the forum, it looks like a Hybrid weighing in the low 80s will appear in due course. Given how well the 80.5gn Fullbore has worked out in practice, that is likely a very sensible move. I cannot see how a workable lead core HPBT 224 with a lower FF value than the current VLD's 90 can be sensibly achieved, so my conclusion FWIW (which is likely not a lot) is that .224 calibre bullet design has peaked in simple ballistics terms (which is a different thing from practicality, useability, and precision).
We won't see anything heavier than 90s either as if you do a scaling exercise as Bryan L and Berger have no doubt done when it comes to what are the practical limits on bullet lengths and designs, the same optimal shape scaled up and down gives you 90gn for 22, 115gn for 6mm, 142gn for 6.5mm 185gn for 7mm, 225gn for .30 (working from memory here on this bit of Bryan's book Applied Ballistics for Long Range Shooting) Some would say that the 90gn VLD form in .224 and the 115gn ditto in 6mm are a scale-step too far as neither works as well for them as some lighter / shorter designs in these calibres.
There are of course other ways of skinning a cat and a notable recent development is the very short bearing surfaces on many recent introductions in all calibres. This allows higher MVs through reduced friction in the bore and also less heat induced stress placed on the bullet. I've no idea if there is any opportunity in this design aspect for the putative 224 Hybrid, but here's hoping.